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DFT Study of Metal (Ag, Au, Pt)-Modified SnS2 for Adsorption of SF6 Decomposition Gases in Gas-Insulated Switchgear.

Langmuir
In this study, the gas-sensitive response of metal (Ag, Au, Pt)-modified SnS2 toward SF6 decomposition gases (SOF2, SO2F2, SO2, H2S) in gas-insulated switchgear was studied by analyzing the adsorption structure, band structure, charge transfer, and ...
Yuhang Wang   +6 more
semanticscholar   +1 more source

Recovery of High-Purity SF6 from Humid SF6/N2 Mixture within a Co(II)-Pyrazolate Framework.

Journal of the American Chemical Society
Sulfur hexafluoride (SF6) is extensively employed in the power industry. However, its emissions significantly contribute to the greenhouse effect. The direct recovery of high purity SF6 from industrial waste gases would benefit its sustainable use, yet ...
Xin Zhang   +5 more
semanticscholar   +1 more source

Mid-infrared quartz-enhanced photoacoustic sensor for ppb-level CO detection in SF6 gas matrix exploiting a T-grooved quartz tuning fork.

Analytical Chemistry, 2020
An optical sensor for highly sensitive detection of carbon monoxide (CO) in sulfur hexafluoride (SF6) was demonstrated by using quartz-enhanced photoacoustic spectroscopy (QEPAS) technique. A spectrophone composed by a custom 8 kHz T-shaped quartz tuning
Bo Sun   +7 more
semanticscholar   +1 more source

Pd-Adsorbed SiN3 Monolayer as a Promising Gas Scavenger for SF6 Partial Discharge Decomposition Components: Insights from the First-Principles Study.

Langmuir
Gas-insulated switchgear (GIS) equipment must be protected by detecting and eliminating the toxic SF6 partial discharge decomposition components. This study employs first-principles calculations to thoroughly investigate the interaction between a Pd ...
Gang Guo   +3 more
semanticscholar   +1 more source

Palladium modified MoS2 monolayer for adsorption and scavenging of SF6 decomposition products: A DFT study

, 2020
Based on the first principle calculation, Pd-doped MoS2 (Pd–MoS2) monolayer has been proposed to adsorb the main decomposition products of SF6: SOF2 and SO2F2.
Tao Li   +4 more
semanticscholar   +1 more source

Photodetachment of SF6−

Chemical Physics Letters, 1995
Abstract The photodetachment cross section for SF 6 − and the photodetachment threshold for this process have been accurately measured using a newly developed technique. The photodetachment cross section has a threshold at 3.16 eV which is about three times larger than the electron affinity of the SF 6 molecule.
P.G. Datskos   +2 more
openaire   +1 more source

Ru-InN Monolayer as a Gas Scavenger to Guard the Operation Status of SF6 Insulation Devices: A First-Principles Theory

IEEE Sensors Journal, 2019
SF6 insulation devices are important components in the power system, wherein the SF6 acts as the insulating gas protecting the operation state of devices effectively.
H. Cui   +3 more
semanticscholar   +1 more source

Infrared intensities in crystalline SF6

Spectrochimica Acta, 1962
Abstract Absolute infrared intensities of solid SF 6 have been measured. The results are v 5 , B = 104,000 cm mmole −1 v 6 , B = 12,200 cm mmole −1 The values represent a 1 per cent decrease and 63 per cent increase, respectively, from the gas phase.
D DOWS, G WIEDER
openaire   +1 more source

Volume electrical discharge in Ne/SF6/C6H14 and pure SF6

Russian Physics Journal, 1999
The electrical and spatial characteristics of a volume electrical discharge are studied as functions of the ratio of partial pressures of the mixture components at varying initial voltage. Early in the discharge, hot (plasma) cathode spots are observed with diffusive plasma flares developing above them.
Yu. I. Bychkov   +2 more
openaire   +1 more source

Partial discharge behavior of protrusion on high voltage conductor in GIS/GIL under high voltage direct current: Comparison of SF6 and SF6 alternative gases

IEEE transactions on dielectrics and electrical insulation, 2020
Recent studies have demonstrated that fluoronitrile (FN) Novec™ 4710 and fluoroketone (FK) Novec™ 5110 show higher dielectric strength than SF6. These gases can be mixed with a buffer gas such as CO2 and technical air to have suitable dielectric ...
C. Toigo   +3 more
semanticscholar   +1 more source

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