Results 241 to 250 of about 241,980 (309)

Room‐Temperature Gas‐Phase CO2‐to‐C3 Coupling by a 4f‐Aromatic Cluster

open access: yesAngewandte Chemie, EarlyView.
We engineered a 4f metalla aromatic cluster, PrB2C2−, that enables efficient sequential C−C coupling with CO2 at room temperature, yielding a linear C3 backbone. This system provides a complete theoretical catalytic cycle and establishes a new design principle for lanthanide mediated CO2 activation.
Feng‐Xiang Zhang   +7 more
wiley   +1 more source

Nucleophilic Gallyl Anions Enable Ga─Au Bimetallic Ammonia Activation

open access: yesAngewandte Chemie, EarlyView.
Unlocking gallyl nucleophiles: Counterion control enables formation of an unsupported gallyl─gold complex. Gold coordination induces a polarity switch at gallium, enabling cooperative activation of NH3 and related N─H/O─H substrates under mild conditions.
Hellen Videa   +3 more
wiley   +1 more source

Magnetic-field-guided catalytic effect mitigates Li<sub>2</sub>S passivation of lithium-sulfur batteries. [PDF]

open access: yesNatl Sci Rev
Liao L   +12 more
europepmc   +1 more source

An Artificial Molecular Pump Powered by Light

open access: yesAngewandte Chemie, EarlyView.
A minimal rotaxane‐based supramolecular system functions as a light‐powered molecular pump, capturing macrocycles from solution and concentrating them within an intramolecular compartment. Repeated azobenzene photoisomerization modulates the binding and kinetic barriers of threading and shuttling, generating a photon‐driven energy ratchet that sustains
Federico Nicoli   +7 more
wiley   +1 more source

Targeted elimination of Staphylococcus aureus mastitis infections with synthetic phage-based CRISPR-Cas delivery systems. [PDF]

open access: yesNPJ Biofilms Microbiomes
Garmendia-Antoñana N   +7 more
europepmc   +1 more source

Review on Cathode Stabilization by Electrolyte Engineering in Aqueous Batteries. [PDF]

open access: yesNanomicro Lett
Zhang R   +6 more
europepmc   +1 more source

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