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Incorporation of Organosilicon Motifs in Natural and Synthetic Small Molecules for Anticancer Therapeutics: Current Perspectives and Future Opportunities in Drug Design [PDF]
MoleculesSilicon is among the most abundant elements on Earth, yet its incorporation into organic molecules is atypical in most biological contexts. However, the strategic introduction of silicon, in line with the demonstrated success of the incorporation of ...
Rushika Raval +6 more
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Hydrogen production from formic acid catalyzed by NHC–Cu complexes [PDF]
Beilstein Journal of Organic ChemistryThe first NHC–Cu-catalyzed decomposition of formic acid (FA) is reported. In the presence of PhSiH3, only hydrogen is generated while CO2 is captured by a silane species.
Orlando Santoro, Catherine S. J. Cazin
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Cardiology Research and Practice, 2022 Introduction. Cardiovascular diseases are the leading cause of death worldwide. The combination of statins and cholesterol-absorption inhibitors promotes the decrease in risk factors, such as high concentrations of LDL (low-density lipoproteins). The aim
Joel Rodríguez-Saldaña +9 more
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Spinning of Endless Bioactive Silicate Glass Fibres for Fibre Reinforcement Applications
Applied Sciences, 2021 Bioactive glasses have been used for many years in the human body as bone substitute. Since bioactive glasses are not readily available in the form of endless thin fibres with diameters below 20 µm, their use is limited to mainly non-load-bearing ...
Julia Eichhorn +12 more
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Green Chemistry Letters and Reviews, 2022 Various commercially available primary and secondary hydrosilanes were exploited for versatile direct dehydrocoupling with alcohols and phenols through cobalt catalysis. The protocol enables efficient Si–O bond formation with a host of O–nucleophiles and
Ewelina Szafoni +2 more
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Silylboronate-Mediated Defluorosilylation of Aryl Fluorides with or without Ni-Catalyst
Frontiers in Chemistry, 2021 The defluorosilylation of aryl fluorides to access aryl silanes was achieved under transition-metal-free conditions via an inert C–F bond activation. The defluorosilylation, mediated by silylboronates and KOtBu, proceeded smoothly at room temperature to ...
Jun Zhou +3 more
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REACTIVITY STUDY OF MERCAPTO–SILANE AND SULFIDE–SILANE WITH POLYMER
Rubber Chemistry and Technology, 2020 ABSTRACT Mercapto–silanes enable an improved silica dispersion state compared with sulfide–silanes in tire tread compounds, which causes a better balance of wet grip and rolling resistance. However, it also causes a higher Mooney viscosity and a shorter scorch time, which results in processing difficulties.
Sato, Masaki +4 more
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Dental Research Journal, 2023 Background: Porcelain fracture or chipping is one of the limitations of all ceramic restorations. This study investigated the shear bond strength (SBS) of composite resins to lithium disilicate ceramics using universal bondings and different methods of ...
Kamyar Fathpour +4 more
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Synthesis of Organoalkoxysilanes: Versatile Organic–Inorganic Building Blocks
Compounds, 2023 Organic–inorganic building blocks are an important class of hybrid materials due to the synergistic versatility of organic compounds with the robust properties of inorganic materials.
Carina I. C. Crucho
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The Role of APTES as a Primer for Polystyrene Coated AA2024-T3
Micromachines, 2023 (3-Aminopropyl)triethoxysilane (APTES) silane possesses one terminal amine group and three ethoxy groups extending from each silicon atom, acting as a crucial interface between organic and inorganic materials.
John Halford, Cheng-fu Chen
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