Results 251 to 260 of about 211,621 (304)

A Ruthenium‐(Ph‐BPE) Catalyst for Asymmetric Alkynylation of Fluoral: Enantioselection From 1 of 12 Fluxional Stereogenic‐at‐Ruthenium Complexes

open access: yesAngewandte Chemie International Edition, EarlyView.
The first enantioselective alkynylations of aqueous fluoral are described. These processes are catalyzed by an iodide‐bound ruthenium‐(Ph‐BPE)‐catalyst; an octahedral metal complex that can exist as 12 diastereomeric‐at‐metal isomers. Calculations reveal that 2 of 12 stereoisomeric complexes account for 99.9% of the Boltzmann population and that ...
Weijia Shen   +6 more
wiley   +1 more source

Optimized Selenium‐Doped Nanocomposites for Enhanced Polymer Gel Performance in Permeability Reduction

open access: yesAsia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT Excessive water production in mature oil fields necessitates robust shut‐off treatments, yet conventional polymer gels often fail under high‐temperature and high‐salinity conditions. This study aims to enhance gel thermal stability and mechanical strength by incorporating selenium‐doped Ag/AgO–ZnO nanocomposites synthesized via a novel green ...
Fadhil F. Sead   +8 more
wiley   +1 more source

Photocatalytic silica gel

open access: yesFocus on Catalysts, 2006
openaire   +1 more source
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Structure of silica gels

Physical Review Letters, 1991
The structure of silica hydrogels has been studied by elastic light scattering. Like colloidal silica gels and neutrally catalyzed aerogels, these gels show mass fractal behavior at length scales below a crossover length \ensuremath{\xi} and scatter like a spatially random distribution of fractal objects for length scales g\ensuremath{\xi}.
F. FERRI, B. J. FRISKEN, D. S. CANNELL
openaire   +3 more sources

Living bacteria in silica gels

Nature Materials, 2002
The encapsulation of enzymes within silica gels has been extensively studied during the past decade for the design of biosensors and bioreactors. Yeast spores and bacteria have also been recently immobilized within silica gels where they retain their enzymatic activity, but the problem of the long-term viability of whole cells in an inorganic matrix ...
Nadine, Nassif   +5 more
openaire   +2 more sources

Crystallization of macromolecules in silica gels

Acta Crystallographica Section D Biological Crystallography, 1994
Procedures are described for the crystallization of proteins, nucleic acids and viruses in a silica-gel matrix using otherwise standard reagents and conditions. Methods are given based on both vapor diffusion in a sitting drop and liquid-liquid diffusion.
R, Cudney, S, Patel, A, McPherson
openaire   +2 more sources

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