Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate
A photoredox strategy employing Martin silicates enables the oxidative generation and controlled capture of cyclopropyl radicals, including the naked one, long considered challenging intermediates. The method affords functionalized cyclopropanes through both Giese‐type additions and dual nickel/photoredox C(sp3)−C(sp2) cross‐couplings.
Amal Lakhal +3 more
wiley +1 more source
Silicon at the Soil-Plant-Microbiome Interface: Rhizospheric Reconfiguration and Crop Resilience to Environmental Stresses. [PDF]
Boutafda A +4 more
europepmc +1 more source
Multivalent RNA‐Cleaving Agents on a Cubic Octameric Silsesquioxane Core
RNA‐cleaving agents on a cubic octameric silsesquioxane core were synthesized and characterized. Several catalytic systems of these structures were screened using hexaribonucleotide models. The best systems were then further used to study their catalytic efficiency in cleaving a HER2 mRNA model sequence. The induced cleavage sites were also determined.
Hanni Haapsaari, Iris Tuomi, Pasi Virta
wiley +1 more source
Setting Characteristics, Solubility, Bioactivity and Interaction with Dentin of Four Calcium Silicate-Based Endodontic Sealers. [PDF]
Vrochari AD +3 more
europepmc +1 more source
Peroxodisulfate‐Enhanced Leaching of Deep‐Sea Manganese Crusts and Sulfides
Ammonium peroxodisulfate enables efficient leaching of deep‐sea manganese crusts and massive sulfides while offering electrolytic recycling. High leaching yields for V, Mn, Co, Mo, Sn, and W, along with complete leaching of As and Sb, highlight its potential as a powerful and sustainable oxidant for marine resource processing.
Bastian Hansel +5 more
wiley +1 more source
Surface-Modified Nickel Foam Cathodes for the Electroflotation of Multi-Component Batik Wastewater. [PDF]
Musawwa MM +10 more
europepmc +1 more source
Abstract This study proposes a novel, green, and sustainable method for synthesizing magnetic iron oxides from metallurgical copper slag (CS), leveraging its iron content as a valuable resource. Iron was extracted via acid leaching using edible citric acid (ECA), forming a citrate–iron complex (CSL), which was subsequently thermally decomposed at 300°C
Melisa Portilla‐Sangabriel +4 more
wiley +1 more source
Electrochemical Lithiation and Delithiation of Amorphous Nonstoichiometric Silicon Oxide Thin-Film Electrode Studied by <i>Operando</i> X-ray Photoelectron Spectroscopy. [PDF]
Iwama T +6 more
europepmc +1 more source
Feasibility Study of Basic Steel Slag as Anode of Li‐Ion Batteries
This study presents a low‐cost, eco‐friendly approach to utilize basic steel slag as a sustainable anode for lithium‐ion batteries, demonstrating good cyclic stability, rate capability, and long‐term electrochemical performance. ABSTRACT The elevated expenses and utilization of hazardous chemicals in traditional chemical synthesis of anode materials of
Rudra Barua +2 more
wiley +1 more source
Extraterrestrial regolith is hemostatic and potentially suitable for hemorrhage control in space. [PDF]
Ali-Mohamad N +6 more
europepmc +1 more source

