Results 51 to 60 of about 38,930 (309)

Supported Ni Single-Atom Catalysts: Synthesis, Structure, and Applications in Thermocatalytic Reactions [PDF]

, 2023
Alina D. Nishchakova, Lyubov G. Bulusheva, Dmitri A. Bulushev   +2 more
openalex   +1 more source

The Multifaceted Reactivity of Single‐Atom Heterogeneous Catalysts [PDF]

Angewandte Chemie International Edition, 2018
AbstractSingle‐atom heterogeneous catalysts (SACs) attached to carefully chosen hosts are attracting considerable interest; principally because they offer maximum utilization per metal atom and are usually readily recyclable. However, diminution of the atomic population of nanoparticles or nanoclusters to single atoms can significantly alter reactivity
Sharon Mitchell, Evgeniya Vorobyeva, Javier Pérez‐Ramírez   +2 more
openaire   +3 more sources

dUTPase is essential in zebrafish development and possesses several single‐nucleotide variants with pronounced structural and functional consequences

FEBS Open Bio, EarlyView.
dUTPases are involved in balancing the appropriate nucleotide pools. We showed that dUTPase is essential for normal development in zebrafish. The different zebrafish genomes contain several single‐nucleotide variations (SNPs) of the dut gene. One of the dUTPase variants displayed drastically lower protein stability and catalytic efficiency as compared ...
Viktória Perey‐Simon, Angéla Békesi, Latifa Kazzazy, Jázmin Mihály, Máté Varga, Beáta G. Vértessy, Kinga Nyíri   +6 more
wiley   +1 more source

Single‐atom catalysts for the electrochemical reduction of carbon dioxide into hydrocarbons and oxygenates

Carbon Energy
The electrochemical reduction of carbon dioxide offers a sound and economically viable technology for the electrification and decarbonization of the chemical and fuel industries.
Karl Adrian Gandionco, Juwon Kim, Lieven Bekaert, Annick Hubin, Jongwoo Lim   +4 more
doaj   +1 more source

Innovative applications of single-atom catalysts in MgH2/Mg system to build high-efficiency hydrogen storage

Journal of Magnesium and Alloys
MgH2 shows significant potential for a solid-state hydrogen storage medium due to the advantages of high hydrogen capacity, excellent reversibility, and low cost.
Lixiang Ma, Lu Zhang, Zhuohan Zhang, Qiuming Peng, Shumin Han, Yuan Li   +5 more
doaj   +1 more source

Single atom catalysts in Van der Waals gaps

Nature Communications, 2022
A family of single-atom catalysts synthesized by intercalating metal single atoms into the van der Waals gap of two-dimensional SnS2 is reported. The materials are applied as hydrogen evolving catalysts with good durability and overpotential.
Huaning Jiang, Weiwei Yang, Mingquan Xu, Erqing Wang, Yi Wei, Wei Liu, Xiaokang Gu, Lixuan Liu, Qian Chen, Pengbo Zhai, Xiaolong Zou, Pulickel M. Ajayan, Wu Zhou, Yongji Gong   +13 more
doaj   +1 more source

Rapid atom-efficient polyolefin plastics hydrogenolysis mediated by a well-defined single-site electrophilic/cationic organo-zirconium catalyst [PDF]

, 2022
Alexander H. Mason, Alessandro Motta, Anusheela Das, Qing Ma, Michael J. Bedzyk, Yosi Kratish, Tobin J. Marks   +6 more
openalex   +1 more source

Enzymatic degradation of biopolymers in amorphous and molten states: mechanisms and applications

FEBS Open Bio, EarlyView.
This review explains how polymer morphology and thermal state shape enzymatic degradation pathways, comparing amorphous and molten biopolymer structures. By integrating structure–reactivity principles with insights from thermodynamics and enzyme engineering, it highlights mechanisms that enable efficient polymer breakdown.
Anđela Pustak, Aleksandra Maršavelski
wiley   +1 more source

A replacement strategy for regulating local environment of single-atom Co-SxN4−x catalysts to facilitate CO2 electroreduction

Nature Communications
The performances of single-atom catalysts are governed by their local coordination environments. Here, a thermal replacement strategy is developed for the synthesis of single-atom catalysts with precisely controlled and adjustable local coordination ...
Jiajing Pei, Huishan Shang, Junjie Mao, Zhe Chen, Rui Sui, Xuejiang Zhang, Danni Zhou, Yu Wang, Fang Zhang, Wei Zhu, Tao Wang, Wenxing Chen, Zhongbin Zhuang   +12 more
doaj   +1 more source

C2α‐carbanion‐protonating glutamate discloses tradeoffs between substrate accommodation and reaction rate in actinobacterial 2‐hydroxyacyl‐CoA lyase

FEBS Open Bio, EarlyView.
Enzymes of the 2‐hydroxyacyl‐CoA lyase group catalyze the condensation of formyl‐CoA with aldehydes or ketones. Thus, by structural adaptation of active sites, practically any pharmaceutically and industrially important 2‐hydroxyacid could be biotechnologically synthesized. Combining crystal structure analysis, active site mutations and kinetic assays,
Michael Zahn, Barbara Seroka, Ryszard Lazny, Zenon Lotowski, Thore Rohwerder   +4 more
wiley   +1 more source