Results 251 to 260 of about 170,894 (344)

Chirality-Induced Suppression of Singlet Oxygen in Lithium-Oxygen Batteries with Extended Cycle Life. [PDF]

open access: yesNanomicro Lett
Chae K   +13 more
europepmc   +1 more source

Boron‐Doping of a Macrocyclic Tetrafuran Framework Unveils an Expanded Porphyrinoid With Switchable (Anti)Aromaticity and Conformational Dynamics

open access: yesAngewandte Chemie, EarlyView.
We disclose a novel boron macrocycle derived from the sustainable furan building block. The boraporphyrinoid exhibits a global antiaromatic ring current and dynamic conformational flexibility. Twofold reduction induces a switch to strong global aromaticity, accompanied by stiffening of the porphyrinoid backbone.
Lukas Swoboda   +6 more
wiley   +2 more sources

Transformation of quercetin by singlet oxygen generated by a photosensitized reaction

open access: hybrid, 1984
Umeo Takahama   +2 more
openalex   +1 more source

Room‐Temperature Gas‐Phase CO2‐to‐C3 Coupling by a 4f‐Aromatic Cluster

open access: yesAngewandte Chemie, EarlyView.
We engineered a 4f metalla aromatic cluster, PrB2C2−, that enables efficient sequential C−C coupling with CO2 at room temperature, yielding a linear C3 backbone. This system provides a complete theoretical catalytic cycle and establishes a new design principle for lanthanide mediated CO2 activation.
Feng‐Xiang Zhang   +7 more
wiley   +2 more sources

Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation

open access: yesAngewandte Chemie, EarlyView.
A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang   +6 more
wiley   +2 more sources

A Deep‐Red‐Absorbing Osmium(II) Complex as a Photosensitizer for Photodynamic Therapy Inducing Immunogenic Cell Death

open access: yesAngewandte Chemie, EarlyView.
A deep‐red‐excited osmium(II) photosensitizer (Os2) induces immunogenic cell death (ICD) under 740 nm irradiation and triggers robust anti‐tumor immune responses both in vitro and in vivo. ABSTRACT Immunogenic cell death (ICD), which converts tumor cells into their own vaccine, plays a pivotal role in the development of novel anticancer therapies. Here,
Yiyi Zhang   +12 more
wiley   +2 more sources

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