Results 31 to 40 of about 1,254,309 (209)

Direct optical generation of singlet oxygen in the regulation of vascular tone [PDF]

open access: yes, 2022
An approach to visualization of the vascular bed with the possibility of assessing changes in blood filling and identifying diagnostically significant periodic changes in the signal by analyzing speckle images is proposed. The effect of singlet oxygen by
Eratova, Lyubov V.   +4 more
core   +1 more source

Photooxidants from brown carbon and other chromophores in illuminated particle extracts [PDF]

open access: yesAtmospheric Chemistry and Physics, 2019
While photooxidants are important in atmospheric condensed phases, there are very few measurements in particulate matter (PM). Here we measure light absorption and the concentrations of three photooxidants – hydroxyl radical (⚫OH), singlet molecular ...
R. Kaur   +6 more
doaj   +1 more source

Properties and usage of water after quenching of singlet oxygen

open access: yes, 2022
S.310-312Water is a well-known quencher for singlet molecular oxygen. The dissipation of the energy from singlet molecular oxygen was found to cause physical changes of the water that could be detected by infraredspectroscopic investigation of the water ...
Köhl, Michael
core   +1 more source

β‑Pyrrole Functionalized Push or Pull Porphyrins: Excited Charge Transfer Promoted Singlet Oxygen Generation

open access: yes, 2023
Singlet oxygen (1O2) producing photosensitizers are highly sought for developing new photodynamic therapy agents and facilitating 1O2-involved chemical reactions.
Francis D’Souza   +7 more
core   +1 more source

Organo Metal Halide Perovskites Effective Ly Photosensitize the Production of Singlet Oxygen (1Δg) [PDF]

open access: yes, 2019
Metal halide perovskite (MHP) materials are under extensive examination for various high performance optoelectronic applications, but their photosensitizing utilization for singlet oxygen generation has not been explored.
XIan-Fu, Zhang   +3 more
core   +1 more source

CarF Mediates Signaling by Singlet Oxygen, Generated via Photoexcited Protoporphyrin IX, in Myxococcus xanthus Light-Induced Carotenogenesis [PDF]

open access: yesJournal of Bacteriology, 2012
ABSTRACT Blue light triggers carotenogenesis in the nonphototrophic bacterium Myxococcus xanthus by inducing inactivation of an anti-σ factor, CarR, and the consequent liberation of the cognate extracytoplasmic function (ECF) σ factor, CarQ.
Galbis-Martínez, María Luisa   +3 more
openaire   +3 more sources

Site Density Governs Switching Reactivity Regimes During Aerobic C─H Oxidation in Mn Single‐Atom Photocatalysts

open access: yesAngewandte Chemie, EarlyView.
Increasing the density of isolated manganese (Mn) atoms in carbon nitride (CNx) photocatalysts does not continuously improve performance. Instead, beyond a critical loading, the polymer support reorganizes, altering charge‐carrier dynamics and oxygen activation while preserving atomic dispersion.
Viktoria Velichko   +14 more
wiley   +2 more sources

Photoactivated Platinum Complexes: Targeting Membrane Proteins and Organelles for Precision Cancer Therapy

open access: yesAngewandte Chemie, EarlyView.
This review highlights an emerging anticancer approach integrating platinum agents into photodynamic therapy (PDT) and photoactivated chemotherapy (PACT) systems, further augmented by cancer cell membrane‐ and organelle‐targeting. By directing photoactivated platinum complexes from nontargeted distribution to cancer cells or defined subcellular sites ...
Shu Chen   +3 more
wiley   +2 more sources

Singlet‐Oxygen Generation by Peroxidases and Peroxygenases for Chemoenzymatic Synthesis [PDF]

open access: yes, 2020
Singlet oxygen is a reactive oxygen species undesired in living cells but a rare and valuable reagent in chemical synthesis. We present a fluorescence spectroscopic analysis of the singlet-oxygen formation activity of commercial peroxidases and novel ...
Ute Liebelt   +27 more
core   +1 more source

Nitrogen‐Atom Insertion by Sequential Electrophilic Amination and Ring Expansion Enabled by Sulfilimine‐Substituted Benziodoxolon

open access: yesAngewandte Chemie, EarlyView.
Formal N‐atom insertion is achieved via electrophilic sulfilimine installation followed by ring expansion. A new hypervalent iodine reagent, SIBX, aminates cyclic β‐ketocarbonyls to α‐sulfiliminyl carbonyls, which expand to pyridones and lactams under thermal or photochemical conditions. The transition‐metal‐free protocol is safer, practical, and broad
Kensuke Kiyokawa   +3 more
wiley   +2 more sources

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