Results 41 to 50 of about 1,254,309 (209)

A subphthalocyanine-pyrene dyad: electron transfer and singlet oxygen generation

open access: yes, 2018
A light harvesting subphthalocyanine-pyrene dyad has been synthesized and characterized by linking pyrene (Py) with subphthalocyanine (SubPc) at its axial position with the B-O bond through the para position of the benzene group.
남원우, Shunichi Fukuzumi
core   +2 more sources

Singlet oxygen production by UV and visible photoexcited porphyrins under different states of aggregation

open access: yesPhotobiochemistry and Photobiophysics, 1986
Tryptophan photosensitization was used to determine the quantum yield of singlet oxygen production by porphyrins irradiated with ultraviolet or visible light in phosphate buffer at pH 7.0. From a preliminary study of aggregation of these dyes, it was established that uroporphyrin, hematoporphyrin and deuteroporphyrin allowed to investigate the ...
Seret, Alain   +2 more
openaire   +2 more sources

Singlet Oxygen Chemistry in Water. 2. Photoexcited Sensitizer Quenching by O2 at the Water−Porous Glass Interface [PDF]

open access: yesThe Journal of Physical Chemistry B, 2008
Insight into the O2 quenching mechanism of a photosensitizer (static or dynamic) would be useful for the design of heterogeneous systems to control the mode of generation of 1O2 in water. Here, we describe the use of a photosensitizer, meso-tetra(N-methyl-4-pyridyl)porphine (1), which was adsorbed onto porous Vycor glass (PVG). A maximum loading of 1.1
Giaimuccio, Jovan   +4 more
openaire   +2 more sources

Singlet-Oxygen-Mediated Synthesis of Pandanusine A and Pandalizine C and Structural Revision of Pandanusine B

open access: yes, 2019
The first synthesis of racemic pandanusines A and B and pandalizine C, isolated from Pandanus amaryllifolius, is reported. The key synthetic step is an efficient tandem reaction sequence initiated by the photooxidation of an easily prepared ...
Myron Triantafyllakis (1796422)   +9 more
core   +1 more source

Tailored Cationic Visible‐Light‐Active Interfaces for Sustainable, Biodegradable Nanofibers With Dual‐Mode Antimicrobial Activity and Robust Electrostatic Particle Capture

open access: yesAdvanced Materials, EarlyView.
Surface co‐functionalization of biodegradable nanofibers with sodium copper chlorophyllin and quaternary ammonium compounds achieves synergistic antimicrobial activity through combined photodynamic and contact‐killing mechanisms. The cationic surface provides humidity‐resistant electrostatic particle capture while maintaining rapid enzymatic ...
Dong Uk Lee   +10 more
wiley   +1 more source

Biofilm‐Binding Phages Enhance Biofilm Eradication by Synergistic Photothermal and Photodynamic Therapy

open access: yesAdvanced Science, EarlyView.
Engineered phage‐based trifunctional nanofibers are developed for synergistic biofilm eradication. Biofilm‐binding phages, armed with AuNPs and TCPP, serve as both warheads and scaffolds, endowing the phototherapy agents with biofilm‐anchoring ability. Upon light irradiation, AuNPs induce photothermal therapy, while TCPP generates 1O2 for photodynamic ...
Ying Cao   +9 more
wiley   +1 more source

Singlet-Oxygen Generation from Individual Semiconducting and Metallic Nanostructures during Near-Infrared Laser Trapping

open access: yes, 2015
Photodynamic therapy has been used for several decades in the treatment of solid tumors through the optical generation of chemically reactive singlet-oxygen molecules (1O2).
Daniel E. Perea (1619320)   +8 more
core   +1 more source

Synergistic Spin‐Polarization and Single‐Atom Engineering in Magnetic Heterojunctions for Efficient Solar Water Splitting

open access: yesAdvanced Science, EarlyView.
High‐throughput screening led to the identification of 67 Z‐scheme heterojunctions (comprising 2D magnetic transition metal halides and non‐magnetic transition metal chalcogenides). For CrI3/MoTe2 and CrI3/WTe2, electronic structure analysis demonstrated that synergistic crystallographic point group and built‐in electric field effects generate a ...
Hongyang Ren   +8 more
wiley   +1 more source

A computational study of possible mechanisms of singlet oxygen generation in miniSOG photoactive protein [PDF]

open access: yes
We report high-level electronic structure calculations of electronic states in the miniSOG (for mini Singlet Oxygen Generator) photoactive protein designed to produce singlet oxygen upon light exposure.
Bella L., Grigorenko   +3 more
core   +2 more sources

Phase‐Resolved Dual Control of Phenol Photodissociation at the Air–Water Interface From Structure‐Resolved Statistics

open access: yesAdvanced Science, EarlyView.
Faster phenol photolysis at the air–water interface arises from two cooperative factors: a more favorable initial microenvironment for solvent‐side electron stabilization, which lowers CI access, and a more labile hydrogen‐bond network, which more readily reorganizes to stabilize the dark‐state intermediate.
Qiang Yin   +8 more
wiley   +1 more source

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