Results 161 to 170 of about 14,717 (257)

Defect‐Rich CoNi Prussian Blue Analogues Enable Highly Selective Electrochemical Hydrogen Peroxide Production

open access: yesAngewandte Chemie, EarlyView.
Introducing [Co(CN)6]3− defects into CoNi Prussian Blue analogues exposes square‐planar Ni–N4 active sites, leading to remarkable H2O2 selectivity during the electrochemical oxygen reduction reaction in alkaline media. ABSTRACT Decentralized electrosynthesis of hydrogen peroxide (H2O2) via the two‐electron oxygen reduction reaction (2e− ORR) offers a ...
Kai Sun   +4 more
wiley   +2 more sources

Temperature‐ and Light‐Regulated Liquid Crystal Smart Window for Dynamic Control of Daylight and Solar Heat in All‐Weather Conditions

open access: yesAngewandte Chemie, EarlyView.
An environmentally adaptive smart window based on the interplay of light‐driven molecular motors and liquid crystal (LC) polymers is developed. The window can dynamically switch among three distinct working states: transparent, reflective, and scattering, depending on ambient temperature and solar light intensity, enabling excellent modulation of ...
Yang Zhang   +6 more
wiley   +2 more sources

Reaction Environment Engineering for Selective C3+ Formation in CO2 Electroreduction: Progress and Perspectives

open access: yesAngewandte Chemie, EarlyView.
This work focuses on how to improve the selectivity and activity of electrocatalytic CO2 reduction to C3+ products, by the integration of electrocatalyst and electrolyte co‐design. We summarize key C3+ formation mechanisms and provide a comprehensive reaction network through thermodynamic analysis.
Ling Chen, Damien Voiry, Yan Jiao
wiley   +2 more sources

Organocatalytic Enantioselective Addition of Malonates to Cyclic Imines: A Short Total Synthesis of Tetraponerine T‐1

open access: yesAngewandte Chemie, EarlyView.
A stereoselective functionalization method of cyclic imines under mild organocatalytic conditions was developed. Bifunctional cinchona alkaloid catalysts combined with carefully optimized reaction conditions to suppress background reactivity enabled highly enantio‐ and diastereoselective addition reactions of malonates to cyclic imines.
Frederic Kölblin, Helma Wennemers
wiley   +2 more sources

A High‐Voltage Membrane‐Free Li–Organic Hybrid Flow Battery Using Eutectic Lithium Chemistry

open access: yesAngewandte Chemie, EarlyView.
A high‐voltage (3.6 V) membrane‐free Li–organic hybrid flow battery is enabled by a deep‐eutectic lithium electrolyte composed of trifluoroacetamide (TFAD) and LiPF6, paired with a dichloromethane (DCM) catholyte containing phenothiazine (PTZ). The TFAD/LiPF6 eutectic provides fast Li+ transport and stable Li‐metal cycling, while the immiscible TFAD ...
Xiao Wang   +7 more
wiley   +2 more sources

Mercury at the Dawn of a New Exploration Phase. [PDF]

open access: yesNat Commun
Del Vecchio E   +2 more
europepmc   +1 more source

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