Results 21 to 30 of about 5,746 (260)

Probing the Na metal solid electrolyte interphase via cryo-transmission electron microscopy

open access: yesNature Communications, 2021
The solid electrolyte interphase (SEI) strongly affects the cycling behaviour of rechargeable alkali metal cells. Here, the authors investigate via cryo-electron microscopy the SEI formed on a Na metal electrode using fluoroethylene carbonate-containing ...
Bing Han   +9 more
doaj   +1 more source

Replacing conventional battery electrolyte additives with dioxolone derivatives for high-energy-density lithium-ion batteries

open access: yesNature Communications, 2021
Interface architecture generated from electrolyte additives is a key element for high performance lithium-ion batteries. Here, the authors present that a stable and spatially deformable solid electrolyte interphase mitigates interfacial degradation of Si-
Sewon Park   +9 more
doaj   +1 more source

Solid Electrolyte Interphases on Sodium Metal Anodes

open access: yesAdvanced Functional Materials, 2020
AbstractSodium metal anodes have attracted significant attention due to their high specific capacity (1166 mA h g−1), low redox potential (−2.71 V vs the standard hydrogen electrode), and abundant natural resources. Nevertheless, unstable solid electrolyte interphases (SEI) and uncontrolled dendrite growth critically hinder their commercialization ...
Changyuan Bao   +7 more
openaire   +3 more sources

Laser desorption/ionization-mass spectrometry for the analysis of interphases in lithium ion batteries

open access: yesiScience, 2023
Summary: Laser desorption/ionization-mass spectrometry (LDI-MS) is introduced as a complementary technique for the analysis of interphases formed at electrode|electrolyte interfaces in lithium ion batteries (LIBs).
Valentin Göldner   +8 more
doaj   +1 more source

How Solid-Electrolyte Interphase Forms in Aqueous Electrolytes

open access: yesJournal of the American Chemical Society, 2017
Solid-electrolyte interphase (SEI) is the key component that enables all advanced electrochemical devices, the best representative of which is Li-ion battery (LIB). It kinetically stabilizes electrolytes at potentials far beyond their thermodynamic stability limits, so that cell reactions could proceed reversibly.
Liumin Suo   +15 more
openaire   +3 more sources

Non-fluorinated non-solvating cosolvent enabling superior performance of lithium metal negative electrode battery

open access: yesNature Communications, 2022
Localised high-concentration electrolyte is key to prevent uneven growth of lithium metal by forming a mechanically stable solid-electrolyte interphase. Here, the authors identify the suitable physicochemical properties for non-solvating co-solvents that
Junyeob Moon   +7 more
doaj   +1 more source

Understanding the failure process of sulfide-based all-solid-state lithium batteries via operando nuclear magnetic resonance spectroscopy

open access: yesNature Communications, 2023
All-solid-state lithium batteries performance is affected by the solid electrolyte interphase (SEI) and electrically disconnected (“dead”) Li metal. Here, via operando NMR measurements, the authors quantify the Li metal in the SEI and “dead” regions ...
Ziteng Liang   +14 more
doaj   +1 more source

Chemical Decomposition of the TFSI Anion under Aqueous Basic Conditions

open access: yesPRX Energy, 2022
Understanding the interfacial reactivity of aqueous electrolytes is crucial for their use in future batteries. We investigate the reactivity of the bis(trifluoromethane)sulfonimide anion when exposed to a strongly basic medium, by means of ab initio ...
Arthur France-Lanord   +5 more
doaj   +1 more source

Solid-Electrolyte Interphases (SEI) in Nonaqueous Aluminum-Ion Batteries [PDF]

open access: yesACS Applied Energy Materials, 2020
Nonaqueous aluminum-ion batteries are an interesting emerging energy storage technology, offering a plethora of advantages over existing grid energy storage solutions. Carbonaceous and graphitic materials are an appealing cathode material in this system, thanks to their low cost and excellent rate capabilities.
Nicolò Canever   +2 more
openaire   +2 more sources

Dual‐Salt Electrolyte Additives Enabled Stable Lithium Metal Anode/Lithium–Manganese‐Rich Cathode Batteries

open access: yesAdvanced Energy & Sustainability Research, 2022
Although lithium (Li) metal anode/lithium–manganese‐rich (LMR) cathode batteries have an ultrahigh energy density, the highly active Li metal and structural deterioration of LMR can make the usage of these batteries difficult.
Junhua Zhou   +10 more
doaj   +1 more source

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