Results 61 to 70 of about 5,746 (260)

A Facile Surface Passivation Method to Stabilized Lithium Metal Anodes Facilitate the Practical Application of Quasi‐Solid‐State Batteries

Advanced Materials Interfaces, 2022
Lithium metal anode matching solid electrolyte is an effective way to achieve high safety and high specific energy batteries, while the active interface of lithium metal has become a bottleneck problem that limits its application. Here, the challenges by
Kangsheng Huang, Jiahui Yu, Langyuan Wu, Zhiwei Li, Hai Xu, Hui Dou, Xiaogang Zhang   +6 more
doaj   +1 more source

Electron‐Induced Molecular Programming Drives Interfacial Chemistry for Ah‐Level Zinc Batteries

Advanced Materials, EarlyView.
We establish an electron‐driven molecular programming strategy that converts spontaneous solid electrolyte interphase formation into a bonding‐defined interfacial architecture. Coordinative integration of p‐bromoaniline with ZnF2 forms a dipole‐regulated molecular lock that reconfigures interfacial electrostatics, suppresses parasitic water reactions ...
Feifei Wang, Yuhang Zhuang, Jiwei Shi, Haojie Zhang, Peng Zhang, Songshan Bi, Hyejung Yang, Wenqiang Yang, Stuart S. P. Parkin, Chunpeng Yang, Quan‐Hong Yang, Ali Shaygan Nia, Xinliang Feng   +12 more
wiley   +1 more source

Undercoordinated Molybdenum Catalysts Enable Ultrafast Quasi‐Solid Sulfur Chemistry in Sodium‐Sulfur Batteries

Advanced Materials, EarlyView.
An unsaturated coordination chemistry strategy activates a quasi‐solid‐state redox pathway by strengthening NaPSs adsorption and accelerating redox conversion kinetics, thereby overcoming the kinetic bottlenecks that limit high‐rate performance. In situ transmission electron microscopy, combined with newly developed Na‐ion diffusion descriptors ...
Mingyue Wang, Yubing Hu, Rui Li, Xinran Gao, Ziwei Tong, Qian Yao, Yameng Fan, Bernt Johannessen, Shixue Dou, Nana Wang, Langli Luo, Guoxiu Wang, Zhongchao Bai   +12 more
wiley   +1 more source

Ultra-thin solid electrolyte interphase evolution and wrinkling processes in molybdenum disulfide-based lithium-ion batteries

Nature Communications, 2019
MoS2 is a highly promising anode material for lithium ion batteries. Here, aided by atomic force microscopy, the authors reveal the formation of an ultra-thin solid electrolyte interphase between MoS2 and electrolyte, providing fresh insight into the ...
Jing Wan, Yang Hao, Yang Shi, Yue-Xian Song, Hui-Juan Yan, Jian Zheng, Rui Wen, Li-Jun Wan   +7 more
doaj   +1 more source

Low Resistance Interphase Formation at the PEO‐LiTFSI|LGPS Interface in Lithium Solid‐State Batteries

Advanced Materials Interfaces, EarlyView.
Interfacial charge transfer and low‐resistance interphase formation between PEO‐based polymer and Li10GeP2S12 solid electrolytes are investigated using multi‐electrode impedance spectroscopy and advanced analytical techniques such as XPS and ToF‐SIMS.
Ujjawal Sigar, Timo Weintraut, Sebastian L. Benz, Semih Engün, Sascha Kremer, Anja Henss, Felix H. Richter   +6 more
wiley   +1 more source

An ultrathin ionomer interphase for high efficiency lithium anode in carbonate based electrolyte

Nature Communications, 2019
The authors here report an ultrathin ionomer membrane as an artificial solid-electrolyte interphase filter that minimizes parasitic reactions and enables stable dendrite-free lithium plating-stripping cycles in a carbonate-based electrolyte.
Yu-Ting Weng, Hao-Wen Liu, Allen Pei, FeiFei Shi, Hansen Wang, Chih-Yuan Lin, Sheng-Siang Huang, Lin-Ya Su, Jyh-Ping Hsu, Chia-Chen Fang, Yi Cui, Nae-Lih Wu   +11 more
doaj   +1 more source

Design of High‐Energy Anode for All‐Solid‐State Lithium Batteries–A Model with Borohydride‐Based Electrolytes

Advanced Materials Interfaces, EarlyView.
This study proposes a function‐sharing anode design to enable nonmetallic lithium insertion while maintaining intimate interfacial contact with the solid‐state electrolyte. A combination of lithium‐compatible and conformable borohydrides, highly conformable indium metal, less‐graphitized acetylene black, and a layer of highly graphitized massive ...
Keita Kurigami, Akihiro Ishii, Itaru Oikawa, Hitoshi Takamura   +3 more
wiley   +1 more source

Phase Diagrams Enable Solid‐State Battery Design

Advanced Materials Interfaces, EarlyView.
Batteries are non‐equilibrium devices with inherent thermodynamic driving forces to react at interfaces, regardless of kinetics or operating conditions. Chemical potential mismatches across interfaces are dissipated via interfacial reactions. In this work, it is illustrated how phase diagrams and chemical potential maps predict degradation pathways but
Nathaniel L. Skeele, Matthias T. Agne
wiley   +1 more source

Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation

Nature Communications, 2019
Zinc chemistry is not favourable to the formation of a solid electrolyte interphase as a result of its high redox potential. In a break with the traditional wisdom, the present authors realise ZnF2-rich hybrid SEI on Zn anode via the modulation of ...
Huayu Qiu, Xiaofan Du, Jingwen Zhao, Yantao Wang, Jiangwei Ju, Zheng Chen, Zhenglin Hu, Dongpeng Yan, Xinhong Zhou, Guanglei Cui   +9 more
doaj   +1 more source

Tailor‐Made Protective LixAlSy Layer for Lithium Anodes to Enhance the Stability of Solid‐State Lithium–Sulfur Batteries

Advanced Materials Interfaces, EarlyView.
An intentionally added, chemically formed LixAlSy coating stabilizes the lithium–electrolyte interface in solid‐state Li–S batteries. The layer suppresses side reactions, preserves smooth charge transfer, and improves ion transport from the start. This approach offers a practical route to more durable solid‐state batteries and a clearer understanding ...
Xinyi Wang, Katja Kretschmer, Sharif Haidar, Georg Garnweitner, Daniel Schröder   +4 more
wiley   +1 more source