Comparative Insights and Overlooked Factors of Interphase Chemistry in Alkali Metal‐Ion Batteries
This review presents a comparative analysis of Li‐, Na‐, and K‐ion batteries, focusing on the critical role of electrode–electrolyte interphases. It especially highlights overlooked aspects such as SEI/CEI misconceptions, binder effects, and self‐discharge relevance, emphasizing the limitations of current understanding and offering strategies for ...
Changhee Lee +3 more
wiley +1 more source
Ni‐rich cathodes in sulfide‐based ASSBs undergo intertwined (electro)chemical and mechanical degradation. Here, a new diagnostic framework is presented to decouple each contribution by partitioning capacity fading into charge and discharge fading.
Jangwhan Seok +12 more
wiley +1 more source
Unveiling the Electrolyte and Solid Electrolyte Interphase in Sodium Ion Batteries: Mechanisms, Progress, and Perspectives. [PDF]
Li M +8 more
europepmc +1 more source
Universal Oxychlorination Strategy in Halide Solid Electrolytes for All‐Solid‐State Batteries
A WO2Cl2‐driven oxychlorination strategy enables bulk oxygen incorporation into close‐packed LixMCl6 (M = Zr, Y, Er, In) halide lattices. Oxygen is selectively anchored by W6+ as lattice‐integrated [WO2Cl4]2− units, regulating the anionic framework, diversifying Li coordination, and weakening Li–Cl interactions.
Jae‐Seung Kim +13 more
wiley +1 more source
Symmetric Vs Asymmetric Imide Anion Decomposition Pathways And Their Influence On Solid Electrolyte Interphase Stability For Si Anodes. [PDF]
Sankaran A +9 more
europepmc +1 more source
Degradation Pathways of Silicon‐Based Anodes in Lithium‐Ion Batteries
Silicon‐based anodes undergo degradation through five primary pathways: (1) mechanical and structural deterioration of the active material, (2) loss of electrode integrity and electrical contact, (3) mechanical instability of the solid electrolyte interphase (SEI), characterized by repetitive fracture and deformation, (4) chemical instability of the ...
Yoon Jeong Choi +3 more
wiley +1 more source
Ultra-Uniform Lithium-Ion Transport Enabled by Supramolecular Polymeric Networks as Artificial Solid Electrolyte Interphase Layers for Highly Stable Lithium-Ion Battery Anodes. [PDF]
Ho JW +14 more
europepmc +1 more source
A combination of discrete and finite element method models for the current collector deformation and electrochemical performance analysis, respectively. The models are calibrated and validated with electrochemical and imaging data of hard carbon electrodes. These electrodes were manufactured with different parameters (slurry solid contents of 35 and 40
Soorya Saravanan +12 more
wiley +1 more source
Cesium Lead Chloride as an Artificial Solid Electrolyte Interphase for Enhanced Anode Protection in Lithium Metal Batteries. [PDF]
Juhi J +6 more
europepmc +1 more source
Emerging Materials and Future Strategies for Solid Oxide Electrochemical Cells
Solid oxide electrochemical cells operate under strongly coupled electrochemical and thermodynamic conditions, where performance is constrained by interactions among crystal structure, defect chemistry, and interfacial evolution. This review, based on a structure‐defect‐property‐durability framework, reveals the roles of lattice symmetry and defect ...
Qiuchun Lu +4 more
wiley +1 more source

