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A ductile solid electrolyte interphase for solid-state batteries

Nature
Solid-state lithium metal batteries are facing huge challenges under practical working conditions1,2. Even when the ionic conductivity of composite solid-state electrolytes is increased to 1 mS cm-1, it is still difficult to realize long-life cycling of solid-state batteries above a current density of 1 mA cm-2 and an areal capacity of 1 mAh cm-2 (ref.
Jinshuo Mi   +25 more
openaire   +2 more sources

Engineering the solid electrolyte interphase as a solid-state electrolyte

Faraday Discussions
A multidimensional design framework in which the SEI emerges as an engineerable, self-assembled composite SSE whose performance is governed by coupled transport, nucleation, and mechanical constraints is presented.
Tianyu Wang   +3 more
openaire   +1 more source

Reactivity and Evolution of Ionic Solid-Electrolyte-Interphases in Battery Electrolytes

ECS Meeting Abstracts, 2021
The instability of the solid electrolyte interphase (SEI) on the lithium (Li) metal anode is a major challenge towards improving the Coulombic efficiency (CE) and cycle life of Li batteries. In classical SEI models with mosaic and layered structures, ionic phases (e.g., Li2O and LiF) are enriched closest to the Li|SEI interface, while the outer SEI ...
Rui Guo   +3 more
openaire   +1 more source

Molecularly Woven Artificial Solid Electrolyte Interphase

Angewandte Chemie
Abstract Lithium‐metal batteries (LMBs) are the most promising candidates for next‐generation high‐energy‐density storage systems, but they suffer from destructive dendrite growth. Here, we integrate cutting‐edge molecular weaving technology into the fabrication of artificial solid electrolyte interphases (ASEI ...
Tianyu Shan   +10 more
openaire   +2 more sources

Structural Properties of Solid Electrolyte Interphase on Lithium Metal

Journal of Nanoscience and Nanotechnology, 2015
To gain an understanding of the structural properties of the solid electrolyte interphase (SEI) created on the surface of lithium during an electrochemical deposition/dissolution reaction in propylene carbonate (PC) containing different concentrations of LiClO4 (1.09, 3.27 mol kg(-1)), the surface of lithium was examined through transmission electron ...
Soon-Ki, Jeong   +2 more
openaire   +2 more sources

Solid Electrolyte Interphase on Lithium Metal Anodes

ChemSusChem
Abstract Lithium metal batteries (LMBs) represent the most promising next‐generation high‐energy density batteries. The solid electrolyte interphase (SEI) film on the lithium metal anode plays a crucial role in regulating lithium deposition and improving the cycling performance of LMBs.
Zhichuan Shen   +5 more
openaire   +2 more sources

Pathways to enabling solid state electrolytically formed batteries: The solid electrolyte interphase

Electrochimica Acta, 2012
Abstract Electrolytically formed batteries (EFB) which start with a single composite between two current collectors, form positive and negative electrodes in situ theoretically allowing complex cell structures and low cost manufacturing. The fundamental challenge of charging shorts which heal upon removal of the current in electrolytically formed ...
W. Yourey   +3 more
openaire   +1 more source

Solid–Electrolyte Interphase of Molecular Crowding Electrolytes

Chemistry of Materials, 2022
Jing Xie   +3 more
openaire   +1 more source

Probing the heterogeneous nature of LiF in solid–electrolyte interphases

Nature
The electrolyte-electrode interface serves as the foundation for a myriad of chemical and physical processes. In battery chemistry, the formation of a well-known solid-electrolyte interphase (SEI) plays a pivotal role in ensuring the reversible operations of rechargeable lithium-ion batteries (LIBs)1,2.
Xiangsi Liu   +15 more
openaire   +2 more sources

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