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A ductile solid electrolyte interphase for solid-state batteries
NatureSolid-state lithium metal batteries are facing huge challenges under practical working conditions1,2. Even when the ionic conductivity of composite solid-state electrolytes is increased to 1 mS cm-1, it is still difficult to realize long-life cycling of solid-state batteries above a current density of 1 mA cm-2 and an areal capacity of 1 mAh cm-2 (ref.
Jinshuo Mi +25 more
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Engineering the solid electrolyte interphase as a solid-state electrolyte
Faraday DiscussionsA multidimensional design framework in which the SEI emerges as an engineerable, self-assembled composite SSE whose performance is governed by coupled transport, nucleation, and mechanical constraints is presented.
Tianyu Wang +3 more
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Reactivity and Evolution of Ionic Solid-Electrolyte-Interphases in Battery Electrolytes
ECS Meeting Abstracts, 2021The instability of the solid electrolyte interphase (SEI) on the lithium (Li) metal anode is a major challenge towards improving the Coulombic efficiency (CE) and cycle life of Li batteries. In classical SEI models with mosaic and layered structures, ionic phases (e.g., Li2O and LiF) are enriched closest to the Li|SEI interface, while the outer SEI ...
Rui Guo +3 more
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Molecularly Woven Artificial Solid Electrolyte Interphase
Angewandte ChemieAbstract Lithium‐metal batteries (LMBs) are the most promising candidates for next‐generation high‐energy‐density storage systems, but they suffer from destructive dendrite growth. Here, we integrate cutting‐edge molecular weaving technology into the fabrication of artificial solid electrolyte interphases (ASEI ...
Tianyu Shan +10 more
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Structural Properties of Solid Electrolyte Interphase on Lithium Metal
Journal of Nanoscience and Nanotechnology, 2015To gain an understanding of the structural properties of the solid electrolyte interphase (SEI) created on the surface of lithium during an electrochemical deposition/dissolution reaction in propylene carbonate (PC) containing different concentrations of LiClO4 (1.09, 3.27 mol kg(-1)), the surface of lithium was examined through transmission electron ...
Soon-Ki, Jeong +2 more
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Solid Electrolyte Interphase on Lithium Metal Anodes
ChemSusChemAbstract Lithium metal batteries (LMBs) represent the most promising next‐generation high‐energy density batteries. The solid electrolyte interphase (SEI) film on the lithium metal anode plays a crucial role in regulating lithium deposition and improving the cycling performance of LMBs.
Zhichuan Shen +5 more
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Breakthrough on understanding the solid electrolyte interphase
Science Bulletin, 2022Shihan, Qi, Xiu, Li, Jianmin, Ma
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Pathways to enabling solid state electrolytically formed batteries: The solid electrolyte interphase
Electrochimica Acta, 2012Abstract Electrolytically formed batteries (EFB) which start with a single composite between two current collectors, form positive and negative electrodes in situ theoretically allowing complex cell structures and low cost manufacturing. The fundamental challenge of charging shorts which heal upon removal of the current in electrolytically formed ...
W. Yourey +3 more
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Solid–Electrolyte Interphase of Molecular Crowding Electrolytes
Chemistry of Materials, 2022Jing Xie +3 more
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Probing the heterogeneous nature of LiF in solid–electrolyte interphases
NatureThe electrolyte-electrode interface serves as the foundation for a myriad of chemical and physical processes. In battery chemistry, the formation of a well-known solid-electrolyte interphase (SEI) plays a pivotal role in ensuring the reversible operations of rechargeable lithium-ion batteries (LIBs)1,2.
Xiangsi Liu +15 more
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