Results 41 to 50 of about 373,610 (343)

Accurate measurement of ^{13}C - ^{15}N distances with solid-state NMR

open access: yes, 2006
Solid-state NMR technique for measureing distances between hetero-nuclei in static powder samples is described. It is based on a two-dimensional single-echo scheme enhanced with adiabatic cross-polarization. As an example, the results for intra-molecular
A. K. Khitrin   +5 more
core   +1 more source

Intermolecular Interactions as Driving Force of Increasing Multiphoton Absorption in a Perylene Diimide‐Based Coordination Polymer

open access: yesAdvanced Functional Materials, EarlyView.
This study uncovers the unexplored role of intermolecular interactions in multiphoton absorption in coordination polymers. By analyzing [Zn2tpda(DMA)2(DMF)0.3], it shows how the electronic coupling of the chromophores and confinement in the MOF enhance two‐and three‐photon absorption.
Simon Nicolas Deger   +11 more
wiley   +1 more source

Structural Information from Solid-State NMR

open access: yesCHIMIA, 1994
The application of selective averaging techniques combined with multidimensional spectroscopy to solid-state NMR structure determination is discussed. Examples include spin-diffusion and spy-diffusion experiments.
Beat H. Meier
doaj   +2 more sources

Interplay between Co-3d and Ce-4f magnetism in CeCoAsO [PDF]

open access: yes, 2010
We have investigated the ground state properties of polycrystalline CeCoAsO by means of magnetization, specific heat and solid state NMR. Susceptibility and specific-heat measurements suggest a ferromagnetic order at about, $T_\mathrm{C}$=75 K.
Baenitz, Michael   +6 more
core   +2 more sources

Solid‐state NMR Structure Determination [PDF]

open access: yesIUBMB Life, 2003
AbstractBiological applications of solid‐state NMR (SS‐NMR) have been predominantly in the area of model membrane systems. Increasingly the focus has been membrane peptides and proteins. SS‐NMR is able to provide information about how the peptides or proteins interact with the lipids or other peptides/proteins in the membrane, their effect on the ...
Alison, Drechsler, Frances, Separovic
openaire   +2 more sources

Enhancing Low‐Temperature Performance of Sodium‐Ion Batteries via Anion‐Solvent Interactions

open access: yesAdvanced Functional Materials, EarlyView.
DOL is introduced into electrolytes as a co‐solvent, increasing slat solubility, ion conductivity, and the de‐solvent process, and forming an anion‐rich solvent shell due to its high interaction with anion. With the above virtues, the batteries using this electrolyte exhibit excellent cycling stability at low temperatures. Abstract Sodium‐ion batteries
Cheng Zheng   +7 more
wiley   +1 more source

Hydrogen-bonded liquid crystals with broad-range blue phases [PDF]

open access: yes, 2019
We report a modular supramolecular approach for the investigation of chirality induction in hydrogen-bonded liquid crystals. An exceptionally broad blue phase with a temperature range of 25 °C was found, which enabled its structural investigation by ...
Dautzenberg E.   +5 more
core   +1 more source

MnI‐Functionalized Covalent Organic Framework as Efficient Electrocatalyst for CO2 Reduction in a Catholyte‐Free Zero‐Gap Electrolyzer

open access: yesAdvanced Functional Materials, EarlyView.
This work demonstrates the successful integration of a phenanthroline‐based 2D COF with MnI catalytic sites into a catholyte‐free membrane‐electrode‐assembly cell for CO2 electroreduction. The crystalline COF actively suppresses Mn⁰–Mn⁰ dimerization, achieving a turnover frequency of 617 h⁻¹ at 2.8 V (full‐cell potential), and enabling stable operation.
Laura Spies   +8 more
wiley   +1 more source

Structure and Dynamics of Spider Silk Studied with Solid-State Nuclear Magnetic Resonance and Molecular Dynamics Simulation

open access: yesMolecules, 2020
This review will introduce very recent studies using solid-state nuclear magnetic resonance (NMR) and molecular dynamics (MD) simulation on the structure and dynamics of spider dragline silks conducted by the author’s research group.
Tetsuo Asakura
doaj   +1 more source

A Theoretical and Experimental Study on the Lewis Acid−Base Adducts (P4E3)·(BX3) (E = S, Se; X = Br, I) and (P4Se3)·(NbCl5) [PDF]

open access: yes, 2001
The Lewis acid−base adducts (P4E3)·(BX3) (E = S, Se; X = Br, I) and (P4Se3)·(NbCl5) have been prepared and characterized by Raman, IR, and solid-state 31P MAS NMR spectroscopy. Hybrid density functional calculations (B3LYP) have been carried out for both
Aubauer, Christoph   +5 more
core   +1 more source

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