Results 51 to 60 of about 397 (163)
Recent advances in heterogeneous catalysis for biomass valorization are highlighted, focusing on furfural, hydroxymethylfurfural (HMF), levulinic acid and glycerol conversion into fuels and chemicals. Metal oxides, zeolites, metal–organic frameworks (MOFs), porous organic polymers (POPs), carbons, and supported metals are compared, emphasizing acid ...
Pratikkumar Lakhani, Atthapon Srifa
wiley +1 more source
We developed a nanostructured catalyst consisting of WO3 nanoparticles and Nb2O5 nanorods for efficient glycerol acetalization to produce a fuel additive (solketal) at room temperature.
Suresh Babu Putla +4 more
doaj +1 more source
An atom‐economic methodology toward the synthesis of β‐adrenergic blocker esmolol (1Ha) from sugarcane bagasse has been developed. The depolymerization of sugarcane via a lignin‐first reductive catalytic fractionation catalyzed by Cu20PMO, enables the selective sourcing of methyl(3‐ (3‐hydroxy‐4‐methoxyphenyl)propionate (1H).
Antonio A. Castillo‐Garcia +1 more
wiley +1 more source
As a means to valorize glycerol, the synthesis of solketal through a ketalization reaction with acetone was performed. Mild solventless conditions were applied to test the activity of different commercially available sulfonic ion exchange resins that had
Esteban Jesús +2 more
doaj +1 more source
Despite efforts to develop polymeric materials using renewable feedstocks, there is a continued reliance on (meth)acrylates for several additive manufacturing (AM) technologies, diminishing their overall sustainability. On the other hand, itaconic acid presents itself as an opportunity to resolve these shortcomings as a biobased source of unsaturation,
James A. Dicks, Srijoni Sengupta
wiley +1 more source
Synthesis of Solketal Fuel Additive From Acetone and Glycerol Using CO2 as Switchable Catalyst
The production of solketal fuel additive was studied from the reaction of glycerol and acetone in the presence of pressurized CO2 as switchable catalyst. A design of experiments (DoE) was used to study the significance of temperature, initial pressure of
Júlia A. C. Nascimento +5 more
doaj +1 more source
Intensification of Ethylene Carbonate Synthesis via Microwave‐Induced Phase‐Change Cycles
Microwave‐assisted heating under ambient pressure reflux conditions is applied to intensify the transesterification of ethylene glycol with dimethyl carbonate. The proposed method enhances energy efficiency and product yield compared to conventional heating, enabling lower catalyst loading, reduced process time, and significantly decreased energy ...
Ioannis Papaioannou +5 more
wiley +1 more source
Abstract Impact in Continuous Flow Heated Mechanochemistry (ICHEM) technology was used for the first biphasic continuous flow esterification of choline chloride‐based deep eutectic solvents (DESs) with nonmiscible acetic, hexanoic, and octanoic anhydrides, resulting in the synthesis of novel hydrotropic DESs.
Qing Liu +5 more
wiley +1 more source
The studies showed that alkaline lipase from Pseudomonas fluorescens enables an irreversible transesterification of vinyl esters to give enantiomeric excess (eeR) of about 80% using vinyl butyrate as acyl donor and diisopropyl ether as a solvent, at ...
Zniszczoł Aurelia +5 more
doaj +1 more source
Sulfonic Acid‐Functionalized KIT‐6 Solid Acid Catalysts for Glycerol Acetylation
Sulfonic acid‐functionalized KIT‐6 (PA‐KIT‐6), synthesized via the post‐synthesis method, is an effective solid acid catalyst for glycerol acetylation, producing triacetin, a promising bio‐additive, along with two other byproducts that are also valuable in the fine chemical industry.
Nattha Baingam +8 more
wiley +1 more source

