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Surfactant solvation effects and micelle formation in ionic liquids
Chemical Communications, 2003The formation of micelles in 1-butyl-3-methyl imidazolium chloride (BMIM-Cl) and hexafluorophosphate (BMIM-PF6) were explored using different surfactants and the solvation behavior of the new micellar-ionic liquid solutions examined using inverse gas chromatography.
Jared L, Anderson +4 more
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Solvation and complex formation in strongly solvating solvents
Pure and Applied Chemistry, 1986Abstract
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Formation and Properties of Solvated Electrons
Angewandte Chemie International Edition in English, 1968AbstractIn the formulation of many chemical reactions, electrons are regarded as readily transferable particles, though their participation in these reactions cannot be directly observed. However, the discovery that electrons can be produced in various ways in suitable solutions and that they are stabilized by solvation and can thus be studied directly
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Screening of Binary Solvent Mixtures and Solvate Formation of Indomethacin
Chemical Engineering & Technology, 2011AbstractThe applicability of solubility parameters and solvent activity in the screening of binary solvent mixtures was studied. The solubility of indomethacin was measured in binary mixtures of dichloromethane, acetone, and ethyl acetate with methanol and ethanol. Solubility extremes in the mixed solvents were observed.
Hellsten, Sanna +2 more
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Pulse radiolytic formation of solvated electrons in hydrazine
Canadian Journal of Chemistry, 1976The spectrum and yield of solvated electrons in anhydrous hydrazine have been investigated by pulse radiolysis. At room temperature the optical absorption band has a maximum at 1.22 eV (1015 nm) with a molar extinction coefficient of 2.2 ± 0.1 × 104 M−1 cm−1 and a temperature coefficient of 1.5 × 10−3 eV deg−1 from 7–45 °C.
William Arthur Seddon +2 more
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Enthalpies of formation and solvation of some organic anions
Faraday Symposia of the Chemical Society, 1975Procedures are described for measuring ΔHD, the enthalpy of deprotonation for organic Bronsted acids in DMSO. Evidence from a number of sources is presented to demonstrate that the deprotonation process is clean and complete.Correlation with Bordwell's pKa data shows that ΔH°D=ΔG°D in DMSO for the compounds considered here.
Edward M. Arnett +3 more
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Enegretics of the Ps Formation: Role of the Solvated Electron
Defect and Diffusion Forum, 2017Taking liquid water as an example, we have considered energetics of the positronium formation. It is shown that quasi-free Ps as well as the Ps localized in a bubble cannot decay into hydrated electron and positron. The most probable value of the positron work function in water, V0+, is 1.5…2 eV.
Sergey V. Stepanov +3 more
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Thermodynamic and Structural Aspects of Solvate Ionic Liquid Formation
2021Development of the electrolyte solution plays a key role in realization for lithium-sulfur (Li–S) battery. The lithium ion local structure and the liquid structures of an electrolyte solution have direct influence on the battery performance because of the electromotive force, the charging/discharging speed and the life time.
Yasuhiro Umebayashi +2 more
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Luminescence of solvate of boron difluoride dibenzoylmethanate with benzene: Aggregates formation
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2014The concentration dependence of spectral-luminescence properties of solutions boron difluoride dibenzoylmethanate (DBMBF2) in benzene and chloroform has been studied through stationary and time-resolved emission spectroscopy methods. The formation of J-aggregates in the solution of DBMBF2 in chloroform has been revealed and a crystalline adduct of ...
E V, Fedorenko +3 more
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