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Thermodynamic Nonideality and Protein Solvation
Although thermodynamic nonideality is usually regarded by physical chemists and biochemists as a complicating factor that should be avoided if possible, the biological world does not seem to share such fears of this phenomenon. Indeed, in view of the highly crowded state of most biological environments, it could be argued that nature has perfected the ...Winzor, Donald J., Wills, Peter R.
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Thermodynamic discontinuity in evaporating thin solvated nematics
The Journal of Chemical PhysicsSelf-organized patterns of nematic liquid crystals (NLCs) are indispensable in sensing and opto-electronics due to their intricate molecular sensitivities. A molecular-scale investigation of solvated thin NLC films reveals that concurrent discontinuities in NLC–NLC interaction-driven thermodynamic properties, mobility, and rheological responses ...
Prateek Chowdhury +2 more
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Thermodynamics of solvation of proteins in guanidine hydrochloride
Biopolymers, 1990AbstractThe interpretation of the thermodynamic quantities of solvation, that is, Gibbs free energy, enthalpy, and entropy changes for the transfer of proteins from water to 6M guanidine hydrochloride, in terms of the thermodynamic transfer parameters of the groups that make up the protein molecule, is unsatisfactory.
Faizan Ahmad, Charles C. Bigelow
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A reassessment of entropy convergence in solvation thermodynamics
Journal of Molecular Liquids, 2018Abstract Entropy convergence is a well-established phenomenon for the hydration of noble gases, hydrocarbons and n-alcohols, whose theoretical explanation has been associated with cavity creation thermodynamics in water. In the last years, computer simulation studies have cast doubts on the occurrence of entropy convergence on increasing the cavity ...
Antonio Grimaldi, Giuseppe Graziano
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Solvation Thermodynamics and Non-Randomness. Part I: Self-Solvation
Journal of Chemical & Engineering Data, 2010The central theme in this series of papers is the development of a coherent and consistent equation-of-state model of fluids in the frame of solvation thermodynamics. Two main ingredients will be used for this purpose: the first will be the successful conductor-like screening model (COSMO) type group-contribution models with their quantum-mechanical ...
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Thermodynamic Analysis of Nifedipine Sublimation, Dissolution and Solvation
The Journal of Chemical Thermodynamics, 2023Angelica V. Sharapova +2 more
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Solvation thermodynamics of completely dissociable solutes
The Journal of Physical Chemistry, 1985On suggere une nouvelle definition de la thermodynamique de solvatation des solutes.
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