Establishing Predictive Models for Solvatochromic Parameters of Ionic Liquids [PDF]
Frontiers in Chemistry, 2019 The use of ionic liquids (ILs) in applications ranging from catalysis to reaction media in organic synthesis has been successfully demonstrated in several cases.
Vishwesh Venkatraman +1 more
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A Method of Calculating the Kamlet–Abboud–Taft Solvatochromic Parameters Using COSMO-RS [PDF]
Molecules, 2019 There is demand for safer and bio-based solvents, brought on by legislation and sustainability objectives. The prediction of physical properties is highly desirable to help design new molecules.
James Sherwood +3 more
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Solvatochromic Parameters of Four Amines in Propane-1,3-diol at 298.15 K [PDF]
MoleculesOne of the most used methods for capturing acidic gases from the atmosphere is the use of amines that react with the acids and can later be recovered.
Maria-Luísa C. J. Moita +3 more
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Prediction of Solvatochromic Polarity Parameters for Aqueous Mixed-Solvent Systems [PDF]
Applied Sciences, 2020 Solvent polarity is important data being used in solvent selections for preliminary engineering design of chemical processes. In this work, a predictive model is proposed for estimating the solvatochromic polarity of electronic transition energy (ET) of ...
Alif Duereh +2 more
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Using new solvatochromic parameters to investigate dye–solvent interactions
Australian Journal of Chemistry, 2022 Solvatochromic behaviours of triazine substituted dyes were evaluated using a novel approach derived from the red shift index (RsI) and associated solvation energy (ASE). These parameters were used to describe the solvation trends of the dye–solvent interactions based on their polarity changes. The concept demonstrates the effect of substituent changes
Victor Akpe +5 more
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Chromotropism of Iron(II) Complexes with Non-Symmetric Heterocyclic Ligands: Polarity Sensing in Aqueous Urea Solutions [PDF]
NanomaterialsThis study reports the synthesis and characterization of two solvatochromic pentacyanoferrate(II) complexes. Their structural design incorporates ligands with flexible xylylene bridges and distinct heterocycles—one combining 4-dimethylaminopyridine (DMAP)
Raffaello Papadakis
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Solvatochromic Polarity, Physicochemical Properties, and Spectral Analysis of New Triple NADES-Based on Urea–Glycerol [PDF]
MoleculesIn the present study, ten type-V natural deep eutectic solvents (NADESs) were synthesized and comprehensively characterized, based on urea as a hydrogen-bond acceptor and three different groups of donors—glycerol, organic carboxylic acids, and ...
Sezan Ahmed +5 more
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Fluorescence Analysis of Local Microenvironments in Polymer Films Using Solvatochromic Dyes [PDF]
SensorsPolymer films and polymer blend films are widely used as functional materials; however, their photophysical behavior cannot be fully explained solely by bulk properties such as relative permittivity or glass transition temperature.
Tomoharu Matsushita +3 more
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Journal of Chromatography A, 1992 Abstract The Snyder measure of solvent eluting strength (ϵ0) in adsorption chromatography correlates well with the molecular dipolarity polarizability (π*), hydrogen bond acidity (α), and hydrogen bond basicity (β) solvatochromic parameters. In addition, the δ correction term to π* is a minor influence but statistically significant.
Dean C. Luehrs +2 more
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Study of the Ternary Mixture of Methanol/Formamide/Acetonitrile via Solvatochromic Probes
MoleculesFollowing previous studies, the ternary mixture of methanol/formamide/acetonitrile (MeOH/Formamide/MeCN) was studied using the UV-Vis absorption spectra at 298.15 K with a set of five probes, 4-nitroaniline, 4-nitroanisole, 4-nitrophenol, N,N-dimethyl-4 ...
Nelson Nunes +2 more
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