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SOLVENT EFFECTS BASED ON PURE SOLVENT SCALES
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
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Solvents and Solvent Effects: An Introduction
Organic Process Research & Development, 2006Solution chemistry is carried out in solvents, that is in liquids under the conditions of application, which can exert a considerable influence on the properties of the dissolved solute species. A short historical overview on the influence of solvents on chemical processes (equilibria, reaction rates) and physical processes (absorption spectra ...
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Side Effects, Solvents, and Co‐Solvents
ChemInform, 2005AbstractFor Abstract see ChemInform Abstract in Full Text.
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Solvent effects on dinucleotide conformation
Journal of Molecular Biology, 1972Abstract The effect of the addition of organic solvents and reagents on the absorption, optical rotatory dispersion and circular dichroism of ApA was investigated. The added reagents were dioxane, ethylene glycol, glycerol, dimethylsulfoxide, trimethylphosphate, guanidine hydrochloride, formamide and tetrahydrofuran.
M J, Lowe, J A, Schellman
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Modeling solvent effects on chiroptical properties
Chirality, 2011AbstractIn this article, the most advanced extensions of solvation models to chiroptical properties of solvated systems will be reviewed. The main aspects determining the complex phenomenon of solvation will be first discussed in terms of the physical interactions beyond them and successively translated in a computational language introducing the ...
MENNUCCI, BENEDETTA +3 more
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Solvent Effects on Chemical Reactivity
Bulletin des Sociétés Chimiques Belges, 1982Abstract
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Solvents and Solvent Effects in Organic Chemistry
2002INTRODUCTION SOLUTE-SOLVENT INTERACTIONS Solutions Intermolecular Forces Solvation Preferential Solvation Micellar Solvation (Solubilization) Ionization and Dissociation CLASSIFICATION OF SOLVENTS Classification of Solvents According to Chemical Constitution Classification of Solvents Using Physical Constants Classification of Solvents in Terms of Acid-
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PHYSIOLOGIC EFFECTS OF INDUSTRIAL SOLVENTS
Journal of the American Medical Association, 1949A glance at the stock shelves of any neighborhood store, even in a small town, shows that chemicals are playing an increasingly important part in our daily life. The grocer sells synthetic detergents; the hardware store, paints, laquers, paint and stain removers; the drugstore, insecticide sprays; the corner gasoline station offers window cleaners and ...
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1975
The substitution of D for H is an elegant probe to use in the elucidation of chemical dynamics, and in particular the solvent isotope effect is a powerful technique for investigating the role of the solvent. This will be the main theme of this chapter. When H2O is replaced by D2O it is inevitable that we are dealing with the effects of substitution at ...
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The substitution of D for H is an elegant probe to use in the elucidation of chemical dynamics, and in particular the solvent isotope effect is a powerful technique for investigating the role of the solvent. This will be the main theme of this chapter. When H2O is replaced by D2O it is inevitable that we are dealing with the effects of substitution at ...
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Solvent effects in vibrational spectroscopy
Transactions of the Faraday Society, 1960The effects of solute-solvent interactions on the frequencies, intensities and shapes of the infra-red absorption bands of dissolved molecules are discussed. The interaction potential energy U between a single solute molecule and its environment is treated as a variable depending upon the solvent configuration and on the normal co-ordinates of the ...
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