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Solvent effect in a “solvent free” reaction
CrystEngComm, 2007Vapour digestion of a mixture of solid [Fe(η5-C5H4–C5H4N)2] and solid pimelic acid HOOC(CH2)5COOH in the presence of solvent vapours generates co-crystals of different stoichiometry depending on the protic or aprotic nature of the solvent. The nature of the products has been ascertained by a combined use of SSNMR and X-ray diffraction.
BRAGA D +6 more
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Study of solute–solvent and solvent–solvent interactions in pure and mixed binary solvents
Journal of Molecular Liquids, 2008Abstract Solute–solvent and solvent–solvent interactions have been studied in fifteen pure solvents and seven binary aqueous mixtures by monitoring the solubility of a dye in the solvents. The standard Gibbs energy of solvation, as given by log s , where s is the solubility has been found to depend on various modes of solute–solvent interaction ...
Angshuman Maitra, Sanjib Bagchi
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Surface second-harmonic generation at air/solvent and solvent/solvent interfaces
J. Chem. Soc., Faraday Trans., 1995The origin of the optical surface second-harmonic response at neat air/liquid and liquid /liquid interfaces is still a matter of debate. To elucidate this question, we first set out the basic equations describing the problem, essentially introducing, in an effective surface susceptibility tensor, the two contributions arising from the response of the ...
Tamburello Luca, A. A. +3 more
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