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The Journal of organic chemistry
The solvolysis rate of 2-bicyclo[3.2.2]nonyl p-toluenesulfonate (6-OTs) was nearly equal to that of cycloheptyl p-toluenesulfonate in 2,2,2-trifluoroethanol (TFE). This indicates that the ethylene bridge in 6-OTs does not significantly enhance the rate and that 6-OTs ionizes without anchimeric assistance.
, Okazaki +3 more
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The solvolysis rate of 2-bicyclo[3.2.2]nonyl p-toluenesulfonate (6-OTs) was nearly equal to that of cycloheptyl p-toluenesulfonate in 2,2,2-trifluoroethanol (TFE). This indicates that the ethylene bridge in 6-OTs does not significantly enhance the rate and that 6-OTs ionizes without anchimeric assistance.
, Okazaki +3 more
openaire +2 more sources
“Carbocation Watching” in Solvolysis Reactions
Angewandte Chemie International Edition, 2008Heike F, Schaller, Herbert, Mayr
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Enzymatic hydrolysis lignin dissolution and low-temperature solvolysis in ethylene glycol
Chemical Engineering Journal, 2023Hong Chen, Yongdan Li
exaly
The Journal of Organic Chemistry, 1970
Donald Duane Roberts, Thomas M. Watson
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Donald Duane Roberts, Thomas M. Watson
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Mechanism of triarylchloroallene solvolysis
Journal of the American Chemical Society, 1971Melvyn D. Schiavelli +3 more
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