Results 81 to 90 of about 173,394 (296)

Engineering Polar Nanoregions in COFs via Controlled Symmetry Breaking Toward Piezocatalysis

open access: yesAngewandte Chemie, EarlyView.
Polar nanoregions (PNRs) are engineered within covalent organic frameworks via asymmetric grafting of highly polar polyfluoroalkyl chains, which enables controlled symmetry breaking. These randomly oriented artificial PNRs dynamically respond to mechanical stimuli and impart relaxation behavior to the COFs (TFB‐TAPT‐FA).
Ge Yan   +13 more
wiley   +2 more sources

Kaolinite and Cd2+ Transport and Interaction in Sand Media: Batch and Column Experiments

open access: yesTerrestrial, Atmospheric and Oceanic Sciences, 2016
Batch sorption and column transport experiments were used to investigate kaolinite colloids and Cd(II) ions (Cd2+) co-transport in water-saturated sand media.
Rakkreat Wikiniyadhanee   +2 more
doaj   +1 more source

Linker‐Locking Strategy for the Rigidification of Flexible Metal–Organic Framework: Structural Stabilization and Controlled ESIPT for H2O/D2O Sensing

open access: yesAdvanced Science, EarlyView.
A linker‐locking strategy rigidifies the flexible metal–organic framework (MOF) MIL‐53‐(OH)2 via the cooperative encapsulation of ligands and structural water. This network significantly enhances the framework's aqueous stability. Crucially, rigidification suppresses enol emission to yield a single keto tautomer state with an extended lifetime ...
Amitosh Sharma   +8 more
wiley   +1 more source

Equilibrium, kinetic and thermodynamic studies for sorption of Ni (II) from aqueous solution using formaldehyde treated waste tea leaves

open access: yesJournal of Saudi Chemical Society, 2015
The sorption characteristic of Ni (II) from aqueous solution using formaldehyde treated waste tea leaves as a low cost sorbent has been studied.
Jasmin Shah   +3 more
doaj   +1 more source

Equilibrium isotherm studies for the sorption of divalent metal ions onto peat: Copper, nickel and lead single component systems [PDF]

open access: yes, 2009
[[abstract]]The sorption of three divalent metal ions – copper, nickel and lead – from aqueous solution onto peat in single component systems has been studied and the equilibrium isotherms determined.
Ho, Y.S.;Porter, J.F.;McKay, G.
core  

Comparison of the Saturated Salt Solution and the Dynamic Vapor Sorption techniques based on the measured sorption isotherm of barley straw

open access: yes, 2017
International audience9 For Heat, Air and Moisture modelling, one of the most crucial hygrothermal properties of porous 10 construction materials is the sorption isotherm. Current techniques for measuring the sorption 11 isotherm rely on the standardized
Jean-Emmanuel Aubert   +5 more
core   +1 more source

Intrinsic Superprotonic Conduction in Metal‐Free Hydrogen‐Bonded Organic–Inorganic Frameworks

open access: yesAdvanced Science, EarlyView.
A simple hybridization strategy yields a suite of metal‐free hydrogen‐bonded organic‐inorganic frameworks (HOIFs) with dense, uninterrupted hydrogen‐bonded networks that possess intrinsically high superprotonic conductivity, establishing a versatile and scalable platform for high‐performance solid‐state proton conductors.
Jin Chen   +14 more
wiley   +1 more source

Rare‐Earth Multivariate Metal–Organic Frameworks: Cationic Radius Biased Compositional Control and Property Tuning

open access: yesAngewandte Chemie, EarlyView.
A family of multivariate metal–organic frameworks, UoB‐116(Ln), can be prepared using up to 16 different metals, revealing the ability to tune properties through compositional control. ABSTRACT The synthesis of a multivariate metal–organic framework (MTV‐MOF) family, [Ln(DNNDI)1.5]n (UoB‐116), is reported (DNNDI: N,N'‐bis(dinicotinate)‐1,4,5,8 ...
Adnan Ishaq   +9 more
wiley   +2 more sources

NH4+ adsorption and adsorption kinetics by sediments in a drinking water reservoir

open access: yesArchives of Environmental Protection, 2016
The sorption isotherm and sorption kinetics of NH4+ by the Fen River reservoir sediment were investigated for a better understanding of the NH4+ sorption characteristics and parameters.
Suna Hongyan, Wanga Xiaoyun
doaj   +1 more source

Engineering an Artificial Metalloenzyme for Efficient Photo‐Enzymatic CO2 Conversion

open access: yesAdvanced Science, EarlyView.
We built a light‐driven artificial metalloenzyme by covalently conjugating formate dehydrogenase (FDH) with a tailored rhodium complex (Rh‐L6) to overcome spatial‐separation‐limited electron transfer. This integration boosts NADH regeneration and CO2 conversion, giving 2.31‐fold higher formate yield than physical mixtures, due to a narrowed bandgap and
Mengxue Kang   +6 more
wiley   +1 more source

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