Results 91 to 100 of about 516,785 (251)
We report a reversible structural phase transition in a metal–organic framework (MOF) triggered by the exchange of coordinative guest molecules. This MOF consists of rigid 1D Pb–O rods as building units, forming a 3D framework with 1D pores. Guest exchange induces pronounced changes in both the Pb–O rod structure and the dimensionality of the framework.
Keisuke Ishikawa, Kazuya Otsubo
wiley +1 more source
Mathematical modeling of sorption isotherms and the thermodynamic properties of vacuum-dried and freeze-dried Barhi dates. [PDF]
Fikry M +6 more
europepmc +1 more source
Combining the chiral bispidine ligand L1 with MnCl2 affords coordination polymers (CPs) with an unusual topology for this family of compounds, consisting of orthogonally packed ribbon‐like one‐dimensional (1D) chains. Their behavior was investigated through single‐crystal‐to‐single‐crystal exchange with aromatic volatile organic compounds (VOCs) and ...
Meriem Goudjil +8 more
wiley +1 more source
Sorption isotherms of edible insect's flours: mathematical modeling and hysteresis. [PDF]
Tejada-Ortigoza V +5 more
europepmc +1 more source
Manganese oxides (MnOX) of different structures and with different Mn oxidation states exhibit significant variation in their reactivity toward the oxidation of allylic alcohols. Using two allylic alcohol model substrates, we demonstrate the relationship between activity and MnOX structure, Mn4+ content and incorporated secondary cations.
Erdogan Kasisari +6 more
wiley +1 more source
Modeling moisture sorption isotherms of milk powders at ambient and elevated temperatures using the dynamic dewpoint isotherm (DDI) method. [PDF]
Kadas E +4 more
europepmc +1 more source
Ru nanoparticles confined within mesoporous SiOx‐pillared montmorillonite exhibit exceptional performance for CO2 methanation. The catalyst maintains a high reaction rate even at elevated CO2 conversion while preserving high Ru mass–specific activity, overcoming typical inhibition by H2O and CO observed in conventional supported Ru catalysts.
Seunghwan Jung +4 more
wiley +1 more source
Dataset and machine learning-based computer-aided tools for modeling working sorption isotherms in dried parchment and green coffee beans. [PDF]
Collazos-Escobar GA +2 more
europepmc +1 more source
Multimodal Fluorescent MOF@BODIPY Platform: Bridging Sensing and Mechanistic Insight
ABSTRACT Hybrid metal–organic frameworks (MOFs) that integrate organic chromophores constitute powerful platforms for optical sensing by combining structural order with tunable photophysics. Incorporating photoresponsive chromophores into MOFs enables sensitive probing of guest–framework interactions through well‐defined luminescent signatures. Herein,
Alejandro Cortés‐Villena +8 more
wiley +1 more source

