Results 141 to 150 of about 167,685 (283)

Rapid and Reusable Amino Acid–Derived MOFs for the Removal of Estrogenic Hormones From Real Water Matrices

Chemistry – A European Journal, EarlyView.
A family of amino‐acid–derived MOFs enables ultrafast (>90–95% in 30 s) simultaneous removal of four estrogenic contaminants from water under SPE conditions. A leucine‐based MOF shows excellent regenerability and robustness in real samples, with structural evidence revealing efficient hormone encapsulation.
Lidia García, Alejandro Cortés‐Villena, Héctor Martínez Pérez‐Cejuela, José Manuel Herrero‐Martínez, Jesús Ferrando‐Soria, Thais Grancha, Donatella Armentano, Emilio Pardo   +7 more
wiley   +1 more source

Impact of A‐Site Sr Substitution in LaFeO3 on Syngas Selectivity During Chemical Looping Dry Reforming of Methane (CL‐DRM)

Chemistry – A European Journal, EarlyView.
Sr doping regulates oxygen exchange and methane activation in LaFeO3, suppressing nonselective CH4 cracking and coke formation during CL‐DRM. La0.7Sr0.3FeO3 provides the optimal balance, delivering ∼40% CH4 conversion, an H2/CO ratio of 2, and >95% carbon balance.
Ganesh Jabotra, Pradeep Kumar Yadav, Lorenzo Stievano, Moulay Tahar Sougrati, Hervé Vezin, Axel Löfberg, Sébastien Royer, Sudhanshu Sharma, Jean‐Philippe Dacquin   +8 more
wiley   +1 more source

Assessing ZIF‐8 Stability for Biomedical Applications Using Fluorescent Probes: Impact of Covalent Conjugation

Chemistry – A European Journal, EarlyView.
Using fluorescein as a probe, we compare PEG (polyethylene glycol) surface coatings of ZIF‐8 (zeolitic imidazolate framework‐8) based on coordinative versus covalent attachment and show that PEG coatings provide only limited protection in phosphate‐buffered saline.
Michael B. Stammler, Hana Bunzen
wiley   +1 more source

Extended batch adsorber analogue model (e‐BAAM) for rapid evaluation of CO2 capture pressure swing adsorption cycles

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract This work presents a simplified extended‐batch adsorber analogue model (e‐BAAM) to quantify key performance metrics such as purity, recovery, and energy trends for various pressure swing adsorption (PSA) process cycles for CO2$$ {\mathrm{CO}}_2 $$ capture.
Gwyneth Liske, Arvind Rajendran
wiley   +1 more source

Application of artificial neural network and general machine learning modelling on CO2 adsorption in moisture equilibrated South African high and medium rank coals

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract This study investigates the effect of moisture on CO2 adsorption in South African coals using both experimental and machine learning approaches. Three coal samples (SL, TN, and EM) with varying ranks (RoVmr: 3.49%, 1.26%, and 0.64%, respectively) were collected from different regions of South Africa.
Kasturie Premlall, Lawrence Koech, Douw Faurie, Khanyisile Lepota   +3 more
wiley   +1 more source

Experimental methods in chemical engineering: Temperature‐programmed oxidation—TPO

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Temperature‐programmed oxidation (TPO) probes the oxidative capacity and redox properties of solid materials—catalysts, metal oxides, perovskites, and carbonaceous deposits. It identifies coke type, distribution, and reactivity. TPO instruments pass an oxidizing gas (diluted O2$$ {\mathrm{O}}_2 $$, air, or less commonly N2O$$ {\mathrm{N}}_2 ...
Gholamreza Roohollahi, Jildimara de Jesus Santana, Alexander R. P. Harrison, Sara Andreoli, Ewa Marek, Stuart Scott, Mohammad Latifi, Gregory S. Patience   +7 more
wiley   +1 more source

Tailoring phosphate mining waste into high‐performance geopolymers: A sustainable process for selective CO2/N2 separation

The Canadian Journal of Chemical Engineering, EarlyView.
Overview of the synthesis, structural features, and CO2 capture performance of geopolymer‐based adsorbents prepared from phosphate mining waste, including granular and spherical materials with high surface area, CO2 capture capacity, and CO2/N2 selectivity.
Alisson Lopes Freire, Mariana Schneider, Ramon Vinícius Santos de Aquino, Enrique Rodríguez‐Castellón, Tirzhá Lins Porto Dantas, Bruno Francisco Oechsler, Humberto Jorge José, Regina de Fátima Peralta Muniz Moreira   +7 more
wiley   +1 more source

Chemically Modular, Nonfluorinated Polymer Adsorbents for Capturing Per‐ and Polyfluoroalkyl Substances (PFAS)

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Nonfluorinated polymer networks for PFAS adsorption are synthesized using active ester click chemistry. Incorporating Lewis base ligands along with hydrophilic and hydrophobic co‐monomers leads to high PFOA binding efficiency. Ligand basicity and pH are found to play an important role in PFOA sorption.
Lakshay K. Dhamania, Joshua D. Moon
wiley   +1 more source

Synergistic Molecular Modulation of ππ Stacking for High‐Performance Pitch‐Derived Hard Carbon Anodes

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A synergistic molecular strategy is demonstrated to disrupt intrinsic ππ stacking in pitch, boosting 6‐fold sulfonation, yielding a hard carbon with 0.371 nm interlayer spacing and maximized closed pores, and achieving a high reversible capacity, remarkable rate capability (205.6 mAh g−1 at 2 A g−1) and cyclic stability.
Xiang Wang, Yangyang Chu, Shuaipeng Liu, Ruyao Zhang, Zeyu Zhu, Qiang Li, Weixiang Li, Ya‐Xia Yin, Sailong Xu   +8 more
wiley   +1 more source

Unveiling Strain‐Driven Catalysis in Magnesium Hydride via Ultrafine High‐Entropy Hydride

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The unprecedented, direct, and tailored synthesis of high‐entropy hydride (HEH) nanoparticles is achieved under ambient conditions via one‐step mechanochemical strategy and demonstrates exceptional catalytic behaviors in magnesium hydride (MgH2) hydrogen storage, where partially dehydrogenated HEH introduces abundant lattice strain and hydrogen ...
Jiaguang Zheng, Changhai Wu, Panpan Zhou, Meiling Lv, Xiulin Fan, Xuezhang Xiao, Lixin Chen   +6 more
wiley   +1 more source