Results 141 to 150 of about 516,785 (251)

Mixed TiO2–SiO2 thin coatings for selective adsorption and sunlight‐powered photodegradation of cationic pollutants

open access: yesResponsive Materials, EarlyView.
Environmental pollution and water scarcity demand innovative purification methods. This study presents a sol‐gel approach to fabricate mixed silica–titania thin films joining photocatalytic activity with selective sorption capability. The films exhibit higher surface area, enhanced degradation of cationic and improved performance over bare titania ...
Andrea Lanfranchi   +13 more
wiley   +1 more source

Surface Engineering of Ti3C2Tx MXenes via Silanol Functionalization for Improved Electrochemical Performance

open access: yesSmall, EarlyView.
This study explores the covalent functionalization of Ti3C2Tx using 5,5′‐bis(triisopropoxysilyl)‐2,2′‐bipyridine in different solvents, revealing that only m‐xylene enables effective covalent bonding, ensuring structural stability and preventing layer swelling.
Abelardo Sánchez‐Oliva   +11 more
wiley   +1 more source

Enhanced Biocatalysis in Nanofluidic Membrane Reactors With Goldilocks Nanopores for Enzymes

open access: yesSmall, EarlyView.
We show that enzyme confinement within the three‐dimensionally interconnected nanochannels of a polyurea molecular network membrane, featuring pore‐size tunability to match the enzyme size, enables a highly active nanofluidic reactor platform. Stable continuous‐flow operation for >200 h and a 30 000‐fold increase in specific space‐time yield over ...
Wangsuk Oh, Ji‐Woong Park
wiley   +1 more source

Impacts of Fluorination at the Ortho‐Position of Carboxy Groups on Tetrakis(biphenyl)ethene‐Based Hydrogen‐Bonded Framework

open access: yesSmall, EarlyView.
This work provides new findings on the effect of fluorination on the substitution of TPE derivatives and the modulation of the structure and fluorescence properties of hydrogen‐bonded organic framework (HOF) of F‐CBPE. ABSTRACT Fluorination of building block molecules is one of the effective engineering approaches to modulate molecular assembly in ...
Takuto Fujii   +8 more
wiley   +1 more source

Polysulfide Immobilization and Sulfur Conversion Kinetics Promotion via a Tetrathiafulvalene–Crown Ether COF@Graphene Layer for High‐Rate Lithium–Sulfur Batteries

open access: yesSmall, EarlyView.
A polysulfide‐regulating covalent organic framework (TUS‐44) integrating tetrathiafulvalene and crown‐ether linkers forms an electron‐delocalized, ion‐coordinative network that synergistically mediates Li–S redox chemistry. When interfaced with graphene, the TUS‐44@G layer functions as a catalytic and chemisorptive interface, enabling efficient ...
Kai Sun   +11 more
wiley   +1 more source

Porous Organic Polymers: From Molecular Design to Scalable Technologies

open access: yesSmall, EarlyView.
This review introduces porous organic polymers (POPs) for a wide range of applications, including energy storage, gas adsorption, catalysts, adsorbents, biomedical applications, sensors, and other exciting fields, and critically analyzes the synthesis and modification, and how structural topology influences the composites' architecture of POPs, along ...
Hossein Mashhadimoslem   +12 more
wiley   +1 more source

Metal‐Free Ternary‐Composite Aerogel Based on Graphitic Carbon Nitride, Graphene Oxide, and β‐Cyclodextrin for Synergistic Adsorption and Photodegradation of Organic Dyes

open access: yesSmall, EarlyView.
A novel metal‐free g‐C3N4/GO/β‐CD aerogel exhibits a high adsorption capacity of 653.2 mg/g for RhB. The synergistic adsorption‐degradation effect of the aerogel enables the complete elimination of organic dyes. Fixed‐bed and recyclability tests demonstrate its potential for continuous industrial wastewater treatment.
Yuan Yu   +8 more
wiley   +1 more source

Interplay Between Oxidation State, Intervalence Charge Transfer Transitions and Electronic Conductivity in a Series of Ru‐Based Metal–Organic Frameworks

open access: yesSmall, EarlyView.
Ru‐based square‐grid metal–organic frameworks undergo dramatic conductivity enhancements after chemical oxidation. The mixed‐valent states exhibit the highest conductivity values, which correlate with the appearance of intervalence charge transfer bands.
Wang Zhang   +12 more
wiley   +1 more source

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