Results 21 to 30 of about 516,785 (251)

COFs on MOFs: Layer‐by‐Layer Synthesis of MOF@COF Nanoparticles with Synergistic Adsorption

Advanced Materials, EarlyView.
A layer‐by‐layer strategy enables the growth of crystalline covalent organic framework (COF) shells on metal–organic framework nanoparticles, creating core–shell structures with tunable porosity. Ordered interstitial mesopores are formed during shell growth, which are connected with the COF's intrinsic micropores, thereby enhancing water sorption. This
Ana Guillem‐Navajas, Lucía Torrico‐García‐Viso, Jose Antonio Suárez del Pino, Nekane Aramburu‐Merino, Pilar Segovia, Enrique G. Michel, Josep Puigmartí‐Luis, Enrique Velasco, Pedro Tarazona, Daniel Maspoch, David Rodríguez‐San‐Miguel, Félix Zamora   +11 more
wiley   +1 more source

High Charge Carrier Mobility in Non‐Conjugated 3D Covalent Organic Frameworks

Advanced Materials, EarlyView.
A non‐conjugated 3D COF constructed via boronate ester linkages from tetraphenylene and pyrene‐based monomers is reported, which exhibits a high charge carrier mobility of 14 ± 1 cm2 V−1 s−1. ABSTRACT π‐Conjugation, π–π stacking, and long‐range order play a central role in determining charge transport efficiency in organic materials.
Joaquín Almarza, Karol Strutyński, Shuai Fu, Yifan Chen, Natalia M. Padial, Isabel del Barrio Gómez, Carlos Martí‐Gastaldo, Andrei N. Khlobystov, Mischa Bonn, Hai I. Wang, Manuel Melle‐Franco, Aurelio Mateo‐Alonso   +11 more
wiley   +1 more source

Modelling the effect of temperature on the water sorption isotherms of chitosan films

, 2016
The interaction of the water molecules from the environment with foods and other materials can be evaluated using sorption isotherms. Films and biodegradable films are susceptible to changes in their functional characteristics due to adsorbed water.
R. Aguirre-Loredo, A. Rodríguez-Hernández, G. Velázquez   +2 more
semanticscholar   +1 more source

Direct Synthesis of High‐Valence Protein@UiO‐66 Composites: Linking Crystallization Pathways to Protein Encapsulation

Advanced Materials, EarlyView.
This work reports a direct, biocompatible method to synthesize UiO‐66, enabling one‐step encapsulation of proteins without compromising crystallinity or activity. Using advanced in situ and ex situ techniques, the study reveals that proteins integrate concurrently with MOF growth, forming crystalline protein@UiO‐66 nanoparticles, and provide insight ...
Jesús Cases Díaz, Jana Glatz, Elisa Merced Olivas, Ramon Pons, Joseph P. Patterson, Mónica Giménez‐Marqués   +5 more
wiley   +1 more source

Evolution‐Driven Bio‐Composite Aerogels for Self‐Adaptive Thermal Regulation and Energy Storage

Advanced Materials, EarlyView.
Inspired by nature's multiphase integration, a single chitosan (CTS)–metal chloride (MCl3) coordination precursor is engineered to enable sequential material and functional evolution. The resulting metal ion‐coordinated chitosan (CTS–M) aerogels exhibit humidity‐adaptive thermal insulation for battery safety, while carbonization yields conductive ...
Xiaoxue Zhang, Xiaodong Wang, Jianping Zeng, Zhihua Zhang, Shanyu Zhao, Jun Shen   +5 more
wiley   +1 more source

sorption isotherm

, 2014
Citation: 'sorption isotherm' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.S05770 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Hybrid Amyloid–Boron Nitride Aerogels for Lightweight Sound Insulation

Advanced Materials, EarlyView.
Amyloid fibrils template the mild formation of boron nitride–rich hybrid aerogels with hierarchical porosity, enhanced BN‐like ordering, and fibril‐reinforced mechanics. These ultralight materials combine thermal stability with strong sound absorption and transmission loss, offering a sustainable bio‐assisted route toward lightweight acoustic shields ...
Mohammad Peydayesh, Andrin Lustgarten, Stefan Schoenwald, Enrico Boschi, My Hanh Bui, Ali Miserez, Felix Donat, Christoph R. Müller, Raffaele Mezzenga   +8 more
wiley   +1 more source

Cornus Mas L. Seed‐Derived Biosorbent for Methylene Blue Removal: Surface Characterization and Biosorption Performance

Advanced Materials Interfaces, EarlyView.
Cornus mas L. seeds are transformed into a high‐performance biosorbent through chemical modification, effectively removing methylene blue from aqueous solutions. Comprehensive characterization and optimization reveal a maximum biosorption capacity of 71.71 mg g−1, establishing this sustainable, cost‐effective material as a promising solution for ...
Hakan Yıldız, Adem Necip, Arslan Yusuf Yüksel   +2 more
wiley   +1 more source

Cysteine-Functionalized Chitosan Magnetic Nano-Based Particles for the Recovery of Light and Heavy Rare Earth Metals: Uptake Kinetics and Sorption Isotherms

Nanomaterials, 2015
Cysteine-functionalized chitosan magnetic nano-based particles were synthesized for the sorption of light and heavy rare earth (RE) metal ions (La(III), Nd(III) and Yb(III)).
A. A. Galhoum, Mohammad G. Mafhouz, Sayed T. Abdel-Rehem, N. A. Gomaa, A. Atia, T. Vincent, E. Guibal   +6 more
semanticscholar   +1 more source

Covalent Attachment of Quaternary Ammonium Group to Geopolymer Surface With Silane Coupling Agent to Enable Simultaneous Adsorption of Cations and Anions

Advanced Materials Interfaces, EarlyView.
Modification of geopolymer surface with a silane coupling agent containing quaternary ammonium group enables the development of dual‐functioning ion exchanger for both cations and anions. In the present study, the performance of this material was demonstrated for the uptake of ammonium and nitrate from water.
Yangmei Yu, Marco Fazzini, Giorgia Franchin, Paolo Colombo, Dario Frascari, Md Faysal Hossain, Priyadharshini Perumal, Tero Luukkonen   +7 more
wiley   +1 more source