Carbon Energy, EarlyView.Kirkendall‐engineered hollow Ni–Mn hexacyanoferrates feature Ni‐tunable shell thickness and uniform alloying, coupling architectural control with electronic stabilization. Composition–morphology co‐optimization suppresses Mn³⁺‐driven Jahn–Teller distortions and lowers charge‐transfer barriers, enabling rapid Zn²⁺ transport and reversible redox.
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