Results 61 to 70 of about 225,307 (327)

Mixed‐Metal Promotion in a Manganese‐Molybdenum Oxynitride as Catalyst to Integrate C─C and C─N Coupling Reactions for the Direct Synthesis of Acetonitrile from Syngas and Ammonia

Advanced Materials, EarlyView.
Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje, Wilson Henao, Tania Rodenas, Patricia Concepción, Virginia Pérez Dieste, Alexander Missyul, Giovanni Agostini, Gonzalo Prieto   +7 more
wiley   +1 more source

Stability and the competition-dispersal trade-off as drivers of speciation and biodiversity gradients

Frontiers in Ecology and Evolution, 2015
The geography of speciation is one of the most contentious topics at the frontier between ecology and evolution. Here, building on previous hypotheses, I propose that ecological constraints on species co-existence mediate the likelihood of speciation ...
Loïc ePellissier
doaj   +1 more source

Beyond Presumptions: Toward Mechanistic Clarity in Metal‐Free Carbon Catalysts for Electrochemical H2O2 Production via Data Science

Advanced Materials, EarlyView.
Metal‐free carbon catalysts enable the sustainable synthesis of hydrogen peroxide via two‐electron oxygen reduction; however, active site complexity continues to hinder reliable interpretation. This review critiques correlation‐based approaches and highlights the importance of orthogonal experimental designs, standardized catalyst passports ...
Dayu Zhu, Hsi‐wen Wu, Xiao Wang, Jie Zhang   +3 more
wiley   +1 more source

Unravelling the Secret of Sulfur Confinement and High Sulfur Utilization in Hybrid Sulfur‐Carbons

Advanced Materials, EarlyView.
Thermal condensation of inverse vulcanized sulfur‐carbon hybrids enables a bottom‐up sulfur confinement strategy, in which a protective carbon phase is progressively constructed around sulfur species. The resulting carbon nanodomains covalently tether sulfur chains and stabilize radical intermediates. This integrated architecture effectively suppresses
Tim Horner, Enis Oğuzhan Eren, Elif Begüm Yılmaz, Jiyong Kim, Ernesto Scoppola, Alexandros Vasileiadis, Nadezda V. Tarakina, Markus Antonietti, Paolo Giusto, Evgeny Senokos   +9 more
wiley   +1 more source

Source identification and driving factor apportionment for soil potentially toxic elements via combining APCS-MLR, UNMIX, PMF and GDM

Scientific Reports
The contamination and quantification of soil potentially toxic elements (PTEs) contamination sources and the determination of driving factors are the premise of soil contamination control.
Cang Gong, Xiang Xia, Mingguo Lan, Youchang Shi, Haichuan Lu, Shunxiang Wang, Ying Chen   +6 more
doaj   +1 more source

Tree of Life Reveals Clock-Like Speciation and Diversification [PDF]

Molecular biology and evolution, 2014
Genomic data are rapidly resolving the tree of living species calibrated to time, the timetree of life, which will provide a framework for research in diverse fields of science. Previous analyses of taxonomically restricted timetrees have found a decline
S. Hedges, Julie Marin, Michael Suleski, Madeline Paymer, Sudhir Kumar   +4 more
semanticscholar   +1 more source

Stabilizing Frustrated Phase Transitions in Selective Oxidation Reactions

Advanced Materials, EarlyView.
Using multimodal operando spectromicroscopy, the frustrated phase transition responsible for selective oxidation over cobalt oxide spinel catalysts is identified, corresponding to combined surface reaction and Mars‐van Krevelen (MvK) dynamics. This regime is disrupted by the formation of mobile vacancies and the depletion of active oxygen at high ...
Luis Sandoval‐Diaz, Thomas Götsch, Daniel Cruz, Maurits Vuijk, Juan M. Lombardi, Markus Pietsch, Kassiogé Dembélé, Adnan Hammud, Karsten Reuter, Christoph Scheurer, Axel Knop‐Gericke, Thomas Lunkenbein   +11 more
wiley   +1 more source

speciation

, 2014
Citation: 'speciation' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.ST06861 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
  +5 more sources

N‐heterocyclic Carbenes as Adhesion Promoters on Aluminum Alloy 6061

Advanced Materials Interfaces, EarlyView.
N‐heterocyclic carbenes as novel non‐toxic surface primers for aluminum alloys for better adhesive bonding, because strong adhesive bonding shouldn't come at the cost of poisoning the human body. The impact of NHC functionalization on adhesive joint strength and durability is also evaluated using a single‐lap‐shear test, following continuous exposure ...
Jashanpreet Kaur, Vikram Singh, Alban Morel, Amélie Ruest, Mark D. Aloisio, Cathleen M. Crudden, Janine Mauzeroll   +6 more
wiley   +1 more source

Light‐Controlled Exposure of Cancer Cells to Reactive Oxygen Species Using Organic Semiconductor Thin Films

Advanced Materials Interfaces, EarlyView.
Spin‐coated films of the conjugated polymer F8T2 (poly (9,9‐dioctylfluorene‐alt‐bithiophene)) generate superoxide at the film‐medium interface, enabling precise delivery of reactive oxygen species (ROS) as visible‐light “ROS patches.” Coated surfaces drive rapid, localised cytotoxicity in MCF7 cancer monolayers under white light, providing a reagent ...
Joe Kaye, Niculina Miron, Benjamin Fortes Mayer, Yukai Shi, Boyuan Chen, Lewis Krzeczkowski, Robert J. E. Westbrook, Saif A. Haque, Ali Salehi‐Reyhani   +8 more
wiley   +1 more source