Results 11 to 20 of about 1,666 (180)

ECD spectroelectrochemistry: A review

open access: yesSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2021
The electronic circular dichroism (ECD) spectroscopy is probably the most important chiraloptical method, and the role of chirality in contemporary chemistry, pharmacy, and material science constantly increases. On the other hand, the electrochemical methods are also very sensitive tools for studying multivarious redox processes.
Krzysztof, Karoń   +2 more
openaire   +2 more sources

Voltammetry and Spectroelectrochemistry of TCNQ in Acetonitrile/RTIL Mixtures

open access: yesMolecules, 2020
Understanding the solvation and ion-pairing interactions of anionic substrates in room-temperature ionic liquids (RTIL) is key for the electrochemical applications of these new classes of solvents.
Abderrahman Atifi, Michael D. Ryan
doaj   +1 more source

Dendritic Gold Nanoparticles Towards Transparent and Electroactive Electrodes [PDF]

open access: yesAnais da Academia Brasileira de Ciências
: The combination of UV-visible absorption and electrochemical experiments (spectroelectrochemistry) enables to obtain highly specific spectroscopic information (in situ and operando) from modified surfaces.
RODRIGO M. IOST   +2 more
doaj   +2 more sources

Bidimensional Spectroelectrochemistry

open access: yesAnalytical Chemistry, 2001
A new methodology is presented to offer the possibility of simultaneously obtaining two different spectroscopic signals in a single spectroelectrochemical experiment. Taking the plane of the electrode surface as a spatial reference, normal-beam and parallel-beam UV-vis absorbance signals are jointly analyzed, revealing important experimental ...
López Palacios, Jesús   +4 more
openaire   +3 more sources

Totally synthetic microperoxidase-11 [PDF]

open access: yesRoyal Society Open Science, 2018
A totally synthetic microperoxidase-11 (MP-11) is reported. Accordingly, the undecapeptide (VQKCAQCHTVE) was synthesized by solid-phase peptide synthesis followed by the thiol-ene click reaction with haemin for reconstitution.
Junichi Tanabe   +7 more
doaj   +1 more source

Electrochemistry of Carbon Materials: Progress in Raman Spectroscopy, Optical Absorption Spectroscopy, and Applications

open access: yesNanomaterials, 2023
This paper is dedicated to the discussion of applications of carbon material in electrochemistry. The paper starts with a general discussion on electrochemical doping. Then, investigations by spectroelectrochemistry are discussed.
Marianna V. Kharlamova   +1 more
doaj   +1 more source

Bis(Triphenylamine)Benzodifuran Chromophores: Synthesis, Electronic Properties and Application in Organic Light-Emitting Diodes

open access: yesFrontiers in Chemistry, 2021
A series of bis(triphenylamine)benzodifuran chromophores have been synthesized and fully characterised. Starting from suitably functionalized benzodifuran (BDF) precursors, two triphenylamine (TPA) moieties are symmetrically coupled to a central BDF unit
Hui Li   +11 more
doaj   +1 more source

Electrosynthesis and Characterization of an Electrochromic Material from 2-(3-Thienyl)ethyl acrylate

open access: yesInternational Journal of Electrochemical Science, 2015
A novel acrylate modified 3-thienylethanol (TE) was synthesized and its electropolymerization led to the formation of corresponding acrylate modified poly(3-thienylethanol) (PTE-AA).
Kaiwen Lin   +5 more
doaj   +1 more source

Electrochemical Switch‐On of Nonlinear Optical Response in a Nitro‐Functionalized Arylimido‐Polyoxometalate

open access: yesAngewandte Chemie, EarlyView.
Reducing a nitro‐derivatized arylimido‐polyoxometalate (POM) reversibly switches on its second‐order NLO response, contrasting with prior donor‐functionalized systems that switch off upon reduction. Attenuation of charge‐transfer (CT) to the POM upon reduction gives a more strongly dipolar imido/π‐bridge to ─NO2 CT, signal enhancement of up to 15× (β ...
Claire F. Jones   +7 more
wiley   +2 more sources

Spectroelectrochemical Determination of Isoprenaline in a Pharmaceutical Sample

open access: yesSensors, 2020
UV/Vis absorption spectroelectrochemistry (SEC) is a multi-response technique that has been commonly used for the characterization of materials and the study of reaction mechanisms. However, it has been scarcely used for quantitative purposes. SEC allows
Fabiola Olmo   +4 more
doaj   +1 more source

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