Results 41 to 50 of about 1,690 (184)

Potential dependent spectroelectrochemistry of electrofluorogenic dyes on indium‐tin oxide

open access: yesElectrochemical Science Advances, 2022
Indium‐tin oxide (ITO) is used in a variety of applications due to its electrical conductivity and optical transparency. Moreover, ITO‐coated glass is a common working electrode for spectroelectrochemistry.
Vignesh Sundaresan   +7 more
doaj   +1 more source

Spectroelectrochemical Enzyme Sensor System for Acetaldehyde Detection in Wine

open access: yesBiosensors, 2022
A new spectroelectrochemical two-enzyme sensor system has been developed for the detection of acetaldehyde in wine. A combination of spectroscopy and electrochemistry improves the analytical features of the electrochemical sensor because the optical ...
David Ibáñez   +3 more
doaj   +1 more source

Controlling Self‐Doping in Conjugated Polyelectrolyte Copolymers to Vary the Threshold Voltage in OECTs

open access: yesAdvanced Electronic Materials, EarlyView.
Two series of self‐doped conjugated polyelectrolytes are synthesized from a non‐self‐dopable building block 3MEEET and a self‐dopable building‐block 3HOT−[TMA+] or 3HOT−[SO3H] enabling precise control over the degree of self‐doping, which in turn directly governs the threshold voltage (VT) in OECTs over a wide range of 700 mV.
Julian Hungenberg   +7 more
wiley   +1 more source

Voltabsorptmetric Study for the One-electron Reduction of Methyl Viologen Using Higher-order Derivative Spectral Method

open access: yesElectrochemistry
A voltabsorptmetric study of redox properties of methyl viologen in an optically transparent thin-layer electrode cell was performed. The obtained UV-visible absorption spectra were analyzed using a higher-order derivative conversion (HODC) method.
Shinya KISHIOKA
doaj   +1 more source

Investigation of the spectroelectrochemical behavior of quercetin isolated from Zanthoxylum bungeanum

open access: yesOpen Chemistry, 2021
Flavonoids are common bioactive components in plants. Quercetin is the most abundant flavonoid in the human diet, accounting for more than half of the total daily consumption of flavonoids.
Wang Jun, Liu Linxiang, Jiang Jianwei
doaj   +1 more source

The Influence of pH and Halide Ions on Cefuroxime Electrochemical Degradation

open access: yesInternational Journal of Electrochemical Science, 2022
An optimal combination of pH and halide ion is considered an effective strategy for the removal of cefuroxime from wastewater accrued from hospitals and clinical laboratories.
Bogdan Tutunaru, Bogdan Oprea
doaj   +1 more source

On the Preparation and Spectroelectrochemical Characterization of Certain 2,5‐Bis(het)aryl Substituted Thiophenes

open access: yesChemElectroChem
In this work, a series of novel 2,5‐bis(het)aryl and 2,5‐bis‐thienyl substituted thiophenes have been synthesized and characterized by ultraviolet‐visible‐near infrared (UV‐Vis‐NIR) absorption and fluorescence spectroscopy as well as cyclic voltammetry ...
Dr. Evgenia Dmitrieva   +3 more
doaj   +1 more source

Tetraruthenium Metallamacrocycles with Potentially Coordinating Appended Functionalities

open access: yesInorganics, 2018
We present four new tetraruthenium macrocycles built from two 1,4-divinylphenylene diruthenium and two isophthalic acid building blocks with peripheral, potentially mono- or tridentate donor functions attached to the isophthalic linkers.
Patrick Anders   +3 more
doaj   +1 more source

Mechanistic Diversity in Photoexcited Radical Redox Chemistry: A Critical Evaluation

open access: yesAngewandte Chemie International Edition, EarlyView.
Many high‐profile examples of photoredox catalysis are proposed to proceed via excitation of an open‐shell intermediate form of the catalyst. However, there is much debate over whether such mechanisms are realistic and, if so, exactly how they can occur.
Samuel J. Horsewill   +3 more
wiley   +1 more source

Electrochemical Switch‐On of Nonlinear Optical Response in a Nitro‐Functionalized Arylimido‐Polyoxometalate

open access: yesAngewandte Chemie, Volume 138, Issue 34, 17 August 2026.
Reducing a nitro‐derivatized arylimido‐polyoxometalate (POM) reversibly switches on its second‐order NLO response, contrasting with prior donor‐functionalized systems that switch off upon reduction. Attenuation of charge‐transfer (CT) to the POM upon reduction gives a more strongly dipolar imido/π‐bridge to ─NO2 CT, signal enhancement of up to 15× (β ...
Claire F. Jones   +7 more
wiley   +2 more sources

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