Results 51 to 60 of about 1,690 (184)

Structural, morphological and spectroelectrochemical characterization of poly (2-ethyl aniline)

Journal of the Brazilian Chemical Society, 2000
In this paper a comparative study of the structure, morphology, and the spectroelectrochemical response of poly (2-ethyl aniline) and polyaniline for different counterions is presented.
Schemid Andreia L., Torresi Susana I. Córdoba de, Bassetto Alessandra N., Carlos Ivani A.   +3 more
doaj  

Redox‐Switchable Optical and Magnetic Properties in a Self‐Assembled Hexanuclear Ni(II) Double‐Decker Complex

Chemistry – A European Journal, EarlyView.
A triangular double‐decker Ni6 complex self‐assembles from Ni(II), TMEDA, and a triphenylene tris dioxolene non‐innocent ligand, with two face‐to‐face tris‐semiquinone decks held by a strong covalent C─C interaction. This rigid scaffold delivers four reversible ligand‐centered redox events: oxidation switches on an intense near‐infrared band and ...
Aristide Colin, Yiting Wang, François Lambert, Régis Guillot, Eric Rivière, Zakaria Halime, Nicolas Suaud, Nathalie Guihéry, Ganping Wang, Thayalan Rajeshkumar, Laurent Maron, Nathalie Bridonneau, Talal Mallah   +12 more
wiley   +1 more source

Synthesis, Spectroscopy and Electrochemistry in Relation to DFT Computed Energies of Ferrocene- and Ruthenocene-Containing β-Diketonato Iridium(III) Heteroleptic Complexes. Structure of [(2-Pyridylphenyl)₂Ir(RcCOCHCOCH₃]

Molecules, 2019
A series of new ferrocene- and ruthenocene-containing iridium(III) heteroleptic complexes of the type [(ppy)2Ir(RCOCHCOR′)], with ppy = 2-pyridylphenyl, R = Fc = FeII(η5-C5H4)(η5-C5H5) and R′ = CH3 (1) or Fc (2), as well as R = Rc =
Blenerhassitt E. Buitendach, Jeanet Conradie, Frederick P. Malan, J. W. (Hans) Niemantsverdriet, Jannie C. Swarts   +4 more
doaj   +1 more source

Experimental methods in chemical engineering: Cyclic voltammetry—CV

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Cyclic voltammetry (CV) is a foundational electroanalytical technique for investigating redox behaviour and evaluating material performance across fields such as molecular electrochemistry, electrocatalysis, sensing, and energy storage. Despite its widespread use, a gap remains between formal electrochemical theory and the practical data ...
Yasser Matos‐Peralta, Christopher Panaritis, JoElen Hagler, Clara Santato, Gregory S. Patience   +4 more
wiley   +1 more source

Hydride Materials for Advanced Electrochemical Energy Storage: Progress and Perspectives

EcoEnergy, EarlyView.
Hydrides are emerging as functional materials for low‐carbon electrochemical energy storage. Complex hydrides provide polyanionic electrolyte frameworks for all‐solid‐state, Li–S, and multivalent batteries; hydride ion conductors enable H− transport for emerging hydride‐based cells; and metal hydrides offer established electrode chemistries for Ni–MH ...
Taehyun Kim, Taegyoung Lee, Huijeong Oh, Shin‐ichi Orimo, Sangryun Kim   +4 more
wiley   +1 more source

Carbon dots in electrochemiluminescence: Mechanisms, interface engineering, and bioanalytical applications

Responsive Materials, EarlyView.
Carbon dots are emerging as versatile electrochemiluminescent nanomaterials whose structure, surface states, and interfacial design jointly determine ECL pathways and performance. This review highlights how mechanistic understanding and materials engineering enable programmable CD‐ECL systems for bioanalysis, imaging, and future intelligent analytical ...
Yuhan Zhao, Zixuan Chen, Jun‐Jie Zhu
wiley   +1 more source

Electrochemical Modulation of Hole Extraction in NiO/Perovskite Bilayers

Advanced Materials Interfaces
Charge extraction (or injection) at the transport layer/lead halide perovskite interface is a decisive process in determining the efficiency of optoelectronic devices.
Xiangtian Chen, Krisztina Sárosi, Bálint Tóth, Barnabás Gilicze, Zsolt Bengery, Károly Mogyorósi, Csaba Janáky, Gergely Ferenc Samu   +7 more
doaj   +1 more source

Polysubstituted ferrocenes as tunable redox mediators

Beilstein Journal of Organic Chemistry, 2018
A series of four ferrocenyl ester compounds, 1-methoxycarbonyl- (1), 1,1’-bis(methoxycarbonyl)- (2), 1,1’,3-tris(methoxycarbonyl)- (3) and 1,1’,3,3’-tetrakis(methoxycarbonyl)ferrocene (4), has been studied with respect to their potential use as redox ...
Sven D. Waniek, Jan Klett, Christoph Förster, Katja Heinze   +3 more
doaj   +1 more source

Mixed TiO2–SiO2 thin coatings for selective adsorption and sunlight‐powered photodegradation of cationic pollutants

Responsive Materials, EarlyView.
Environmental pollution and water scarcity demand innovative purification methods. This study presents a sol‐gel approach to fabricate mixed silica–titania thin films joining photocatalytic activity with selective sorption capability. The films exhibit higher surface area, enhanced degradation of cationic and improved performance over bare titania ...
Andrea Lanfranchi, Simone Bertucci, Margherita Peragallo, Fabiano Martorelli, Giovanni Manfredi, Davide Avanzino, Roberto Spotorno, Stefano Alberti, Davide Comoretto, Francesco Di Stasio, Maddalena Patrini, Federico Locardi, Mirko Prato, Paola Lova   +13 more
wiley   +1 more source

<em>In Situ</em> Electrochemical SFG/DFG Study of CN⁻ and Nitrile Adsorption at Au from 1-Butyl-1-methyl-pyrrolidinium Bis(trifluoromethylsulfonyl) Amide Ionic Liquid ([BMP][TFSA]) Containing 4-{2-[1-(2-Cyanoethyl)-1,2,3,4-tetrahydroquinolin-6-yl]diazenyl} Benzonitrile (CTDB) and K[Au(CN)₂]

Molecules, 2012
In this paper we report an<em> in situ</em> electrochemical Sum-/Difference Frequency Generation (SFG/DFG) spectroscopy investigation of the adsorption of nitrile and CN⁻ from the ionic liquid 1-butyl-1-methyl ...
Benedetto Bozzini, Bertrand Busson, Audrey Gayral, Christophe Humbert, Claudio Mele, Catherine Six, Abderrahmane Tadjeddine   +6 more
doaj   +1 more source