Results 51 to 60 of about 1,666 (180)
Ion‐Pairing and Counterion Effects in Contemporary Photochemistry
Ion‐pairing and counterion effects have emerged as fundamental yet underexplored determinants of photochemical behavior. Far from inert, counterions, and Coulombic interactions modulate excited‐state dynamics, quenching efficiencies, emission, and catalytic pathways.
Matthias Schmitz, Christoph Kerzig
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Tetracene and bis(tri(isopropyl)silylethynyl)tetracene (TIPS‐tetracene) exhibit characteristic similarities and differences in their electrochemical redox behavior depending on the base solvent of the electrolyte. Analysis of cyclic voltammograms allows the quantification of substituent and solvent effects and the calculation of an “electrochemical gap.
Holger F. Bettinger +2 more
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Structural, morphological and spectroelectrochemical characterization of poly (2-ethyl aniline)
In this paper a comparative study of the structure, morphology, and the spectroelectrochemical response of poly (2-ethyl aniline) and polyaniline for different counterions is presented.
Schemid Andreia L. +3 more
doaj
A series of new ferrocene- and ruthenocene-containing iridium(III) heteroleptic complexes of the type [(ppy)2Ir(RCOCHCOR′)], with ppy = 2-pyridylphenyl, R = Fc = FeII(η5-C5H4)(η5-C5H5) and R′ = CH3 (1) or Fc (2), as well as R = Rc =
Blenerhassitt E. Buitendach +4 more
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Electrochromic polymer stability under overpotential is improved by inserting an ultrathin, transparent n‐doped poly(benzodifurandione) interlayer between indium tin oxide and a poly(3,4‐propylenedioxythiophene)‐based electrochromic polymer. The interlayer supports rapid switching at operating bias, then becomes resistive near +0.8 V to suppress excess
Priyanka Rout +4 more
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The dithienophosphinine system is a highly versatile conjugated scaffold with strongly pronounced electron‐acceptor characteristics that lead to persistent radical anions. The electronic properties can effectively be tuned by P‐chemistry avenues and keto group modification, as well as π‐extension of the core.
Amaar Hussein +9 more
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Overview of thermal field–enhanced electro‐, photo‐, and photoelectrocatalytic processes: fundamentals, material design, and applications. As a very attractive approach to energy conversion and storage, electrocatalytic, photocatalytic, and photoelectrocatalytic strategies have gained increasing attention in the past decades.
Ziyi Qiao +6 more
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Electrochemical Modulation of Hole Extraction in NiO/Perovskite Bilayers
Charge extraction (or injection) at the transport layer/lead halide perovskite interface is a decisive process in determining the efficiency of optoelectronic devices.
Xiangtian Chen +7 more
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Polysubstituted ferrocenes as tunable redox mediators
A series of four ferrocenyl ester compounds, 1-methoxycarbonyl- (1), 1,1’-bis(methoxycarbonyl)- (2), 1,1’,3-tris(methoxycarbonyl)- (3) and 1,1’,3,3’-tetrakis(methoxycarbonyl)ferrocene (4), has been studied with respect to their potential use as redox ...
Sven D. Waniek +3 more
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Thermocatalytic and electrochemical catalytic conversion/reduction of CO2 offer unique advantages yet face common issues at the electrode/electrolyte interface and toward process optimization and industrialization. This review discusses integrated strategies focused on long‐term catalyst stability and enhanced energy efficiency for achieving economic ...
Xuexue Pan +7 more
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