For the first time, we shed light on the surface‐to‐bulk diffusion, induction, and reaction behaviors of OH−, H+, and H2O species on model oxides for alkaline hydrogen‐evolving reaction (HER). We first demonstrate that bulk OH− diffusion significantly affects the generation of proton sources and the diffusion/reaction behaviors of protons, thus ...
Daqin Guan +12 more
wiley +1 more source
Raman-guided sample subset selection for cost-efficient offline calibration in bioprocesses. [PDF]
Wilms T, Schwenke F, King R, Knorn S.
europepmc +1 more source
The mechanical performance of nanocellular polyetherimide cannot be explained by nanoporosity alone. It is shown that CO2 saturation and desorption leave a distinct mechanical signature in the glassy matrix before foaming. This matrix contribution provides a new route to understand and optimize the brittle to ductile transition in nanocellular polymers.
Félix Lizalde‐Arroyo +7 more
wiley +1 more source
Comparative Experimental Raman, DFT, and Chemometric Characterization of Selected Phenolic Acids: Structural and Environmental Contributions to the Vibrational Response. [PDF]
Palomo JAP +2 more
europepmc +1 more source
Defect‐Templated Phase Engineering in Atomically Thin Metals
Graphene defects are transformed from passive imperfections into programmable templates for phase‐selective growth of atomically thin silver. Plasma‐generated boundary defects favor Ag(1), whereas sp3‐rich zero‐layer graphene promotes Ag(2). This defect‐directed intercalation links local graphene chemistry to crystalline phase, electronic structure ...
Arpit Jain +25 more
wiley +1 more source
Characterizing the Influence of Filter Substrates on Raman Measurements of Microplastics. [PDF]
Shiwani S +4 more
europepmc +1 more source
Electropolymerized Aptasensor for Femtogram‐Level Cytokine Detection
Electropolymerization of 3‐amino‐ʟ‐tyrosine creates ultrathin, smooth, and chemically robust pALT nanofilms with accessible carboxyl functionalities for direct aptamer immobilization. Integrated with fiber‐optic SPR and OECT platforms, these interfaces enable IL‐6 detection down to 100 fg mL−1 and provide a versatile route to bioelectronic sensing ...
Jiyao Yu +7 more
wiley +1 more source
Solid-State Luminescence of an Americium(III) β-Diketonate Complex: Structure and Spectroscopic Characterization of [Am(acac)2(μ-acac)(H2O)]2. [PDF]
McCusker TL +5 more
europepmc +1 more source
Moiré‐Induced Symmetry Breaking of Charge Order in van der Waals Heterostructures
A uniaxial moiré potential in misfit (MS)1+δTaS2 heterostructures selectively reshape charge order: the embedded 1H‐TaS2 layer hosts an incommensurate charge‐density wave, fragmented into nanometer domains and stripped of threefold symmetry. Superconductivity, however, remains uniform and fully gapped, revealing heterosymmetry stacking as a selective ...
Sandra Sajan +12 more
wiley +1 more source
Evaluating the Efficacy of Sunscreen Formulas in Reducing UV Filter Permeation Into the Stratum Corneum via In Vivo Confocal Raman Spectroscopy: Insights and Applications for Practical Suncare Product Design. [PDF]
Zhang T +8 more
europepmc +1 more source

