Results 41 to 50 of about 9,518 (160)

Crystal structure and magnetic properties of (tris{4-[1-(2-methoxyethyl)imidazol-2-yl]-3-azabut-3-enyl}amine)iron(II) bis(hexafluoridophosphate)

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2019
In the complex cation of the title compound, [Fe(C27H41N10O3)](PF6)2, the tripodal tris{4-[1-(2-methoxyethyl)imidazol-2-yl]-3-azabut-3-enyl}amine ligand is coordinated to an FeII ion through the nitrogen atoms of three imidazole and three imino groups ...
Kateryna Znovjyak   +4 more
doaj   +1 more source

Pressure and Temperature Spin Crossover Sensors with Optical Detection

open access: yesSensors, 2012
Iron(II) spin crossover molecular materials are made of coordination centres switchable between two states by temperature, pressure or a visible light irradiation.
Epiphane Codjovi   +2 more
doaj   +1 more source

spin crossover

open access: yes, 2014
Citation: 'spin crossover' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.ST07104 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Design and Control of Cooperativity in Spin-Crossover in Metal–Organic Complexes: A Theoretical Overview

open access: yesInorganics, 2017
Metal organic complexes consisting of transition metal centers linked by organic ligands, may show bistability which enables the system to be observed in two different electronic states depending on external condition.
Hrishit Banerjee   +2 more
doaj   +1 more source

Tuning the Spin States of Two Apical Iron(II) Ions in a Pentanuclear Iron(II) Cluster Helicate through the Choice of Anions

open access: yesCrystals, 2018
Spin-crossover clusters with iron(II) high nuclearity are rare. By using 3,5-bis(pyridin-2-yl)-1,2,4-triazole (bptH) as the ligand with two bidentate chelating sites, we successfully obtained three pentanuclear iron(II) cluster helicate compounds [{FeII ...
Kuan-Hui Fan   +4 more
doaj   +1 more source

Spin drift and spin diffusion currents in semiconductors

open access: yesScience and Technology of Advanced Materials, 2008
On the basis of a spin drift-diffusion model, we show how the spin current is composed and find that spin drift and spin diffusion contribute additively to the spin current, where the spin diffusion current decreases with electric field while the spin ...
M Idrish Miah
doaj  

Research Update: The mechanocaloric potential of spin crossover compounds

open access: yesAPL Materials, 2016
We present a first evaluation of the potential for spin crossover (SCO) compounds to be considered as a new class of giant mechanocaloric effect materials. From literature data on the variation of the spin crossover temperature with pressure, we estimate
Karl G. Sandeman
doaj   +1 more source

Dynamical limits for the molecular switching in a photoexcited material revealed by X-ray diffraction

open access: yesCommunications Physics, 2022
Ultrafast methods have the ability to transiently decouple transitions between subsystems that evolve simultaneously at thermal equilibrium. Here, time-resolved X-ray diffraction reveals a time delay between volumetric and spin-state switching in a spin ...
Alix Volte   +16 more
doaj   +1 more source

Crossovers in spin-boson and central spin models [PDF]

open access: yesChemical Physics, 2004
We discuss how the crossovers in models like spin-boson model are changed by adding the coupling of the central spin to localised modes- the latter modelled as a 'spin bath'. These modes contain most of the environmental entropy and energy at low T in solid-state systems.
Stamp, P. C. E., Tupitsyn, I. S.
openaire   +2 more sources

Spin State Behavior of A Spin-Crossover Iron(II) Complex with N,N′-Disubstituted 2,6-bis(pyrazol-3-yl)pyridine: A Combined Study by X-ray Diffraction and NMR Spectroscopy

open access: yesCrystals, 2020
A series of three different solvatomorphs of a new iron(II) complex with N,N′-disubstituted 2,6-bis(pyrazol-3-yl)pyridine, including those with the same lattice solvent, has been identified by X-ray diffraction under the same crystallization conditions ...
Elizaveta K. Melnikova   +4 more
doaj   +1 more source

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