Results 21 to 30 of about 9,476 (210)
Magnetochemistry, 2021 The embedding of spin-crossover micro- or nanocrystals in various surroundings dramatically changes their functionalities based on first-order spin transitions.
Diana Plesca +6 more
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Inorganics, 2018 Spin-crossover (SCO) is a spin-state switching phenomenon between a high-spin (HS) and low-spin (LS) electronic configurations in a transition metal center.
Kazuyuki Takahashi
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Investigation of a Tetrathiafulvalene-Based Fe2+ Thermal Spin Crossover Assembled on Gold Surface
Magnetochemistry, 2022 A thick film and a monolayer of tetrathiafulvalene-based Fe2+ spin-crossover complex have been deposited by solution on a Au (111) substrate, attempting both self-assembling monolayer protocol and a simpler drop-casting procedure.
Niccolò Giaconi +11 more
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The Effect of Ligand Design on Metal Ion Spin State—Lessons from Spin Crossover Complexes
Crystals, 2016 The relationship between chemical structure and spin state in a transition metal complex has an important bearing on mechanistic bioinorganic chemistry, catalysis by base metals, and the design of spin crossover materials.
Malcolm A. Halcrow
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Role of the impurities in 2D spin crossover nanoparticle: Monte Carlo study
Фізика і хімія твердого тіла, 2023 This work is devoted to the study of the impurities effect in 2D spin crossover nanosystem in frame work of an Ising-like model. Results were obtained by means of Monte Carlo modeling technique, based on the heat bath algorithm.
V. Ivashko, O. Krulikovskyi, A. Samila
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Magnetochemistry, 2022 Structural and magnetic properties of a new spin crossover complex [Mn(4,6-diOMe-sal2323)]+ in lattices with ClO4−, (1), NO3−, (2), BF4−, (3), CF3SO3−, (4), and Cl− (5) counterions are reported. Comparison with the magnetostructural properties of the C6,
Komala Pandurangan +9 more
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Solution-State Spin Crossover in a Family of [Fe(L)2(CH3CN)2](BF4)2 Complexes
Magnetochemistry, 2019 We report herein on five new Fe(II) complexes of general formula [Fe(L)2(NCCH3)2](BF4)2•xCH3CN (L = substituted 2-pyridylimine-based ligands). The influence of proximally located electron withdrawing groups (e.g., NO2, CN, CF3, Cl, Br) bound to ...
Benjamin H. Wilson +5 more
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Advanced Engineering Materials, EarlyView.Disordered (Fe50Co50)1−xPtx thin films exhibit a pronounced anomalous Nernst effect (ANE) with a strong composition dependence on both rigid and flexible substrates. The transverse thermoelectric response peaks near 22.5 at.% Pt, accompanied by enhanced αxy/σxy scaling, thermal transport, and ANE sensitivity.
Mojtaba Mohammadi +2 more
wiley +1 more source
Advanced Engineering Materials, EarlyView.Coarse‐grained (left) and atomistic (right) models of the shape memory polymer ESTANE ETE 75DT3 are shown schematically. The two representations bridge molecular detail and mesoscopic description. Both models capture shape memory behavior, linking segmental mobility and conformational relaxation of anisotropic chains to macroscopic recovery, and ...
Fathollah Varnik
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Magnetic Field Perturbations to a Soft X-ray-Activated Fe (II) Molecular Spin State Transition
Magnetochemistry, 2021 The X-ray-induced spin crossover transition of an Fe (II) molecular thin film in the presence and absence of a magnetic field has been investigated. The thermal activation energy barrier in the soft X-ray activation of the spin crossover transition for ...
Guanhua Hao +12 more
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