Results 11 to 20 of about 9,476 (210)

Metal Substitution Effect on a Three-Dimensional Cyanido-Bridged Fe Spin-Crossover Network

open access: yesInorganics, 2017
We report the CoII-substitution effect on a cyanido-bridged three-dimensional FeII spin-crossover network, Fe2[Nb(CN)8](4-pyridinealdoxime)8·2H2O. A series of iron–cobalt octacyanidoniobate, (FexCo1−x)2[Nb(CN)8](4-pyridinealdoxime)8·zH2O, was prepared ...
Kenta Imoto   +2 more
doaj   +1 more source

Anomalous Pressure Effects on the Electrical Conductivity of the Spin Crossover Complex [Fe(pyrazine){Au(CN)2}2]

open access: yesMagnetochemistry, 2020
We studied the spin-state dependence of the electrical conductivity of two nanocrystalline powder samples of the spin crossover complex [Fe(pyrazine){Au(CN)2}2].
Andrei-Cristian Gheorghe   +9 more
doaj   +1 more source

Spin state switching in iron coordination compounds

open access: yesBeilstein Journal of Organic Chemistry, 2013
The article deals with coordination compounds of iron(II) that may exhibit thermally induced spin transition, known as spin crossover, depending on the nature of the coordinating ligand sphere. Spin transition in such compounds also occurs under pressure
Philipp Gütlich   +2 more
doaj   +1 more source

Exploring the Effects of Synthetic and Postsynthetic Grinding on the Properties of the Spin Crossover Material [Fe(atrz)3](BF4)2 (atrz = 4-Amino-4H-1,2,4-Triazole)

open access: yesMagnetochemistry, 2020
The effects of mechanochemical synthesis and postsynthetic grinding on the spin crossover material [Fe(atrz)3](BF4)2 was examined in detail using a combination of X-ray diffraction, magnetometry, EXAFS and TEM.
Jed H. Askew   +4 more
doaj   +1 more source

Evolution of cooperativity in the spin transition of an iron(II) complex on a graphite surface

open access: yesNature Communications, 2018
Spin-crossover molecules offer a potential route towards molecular spintronics, but retaining the bistability of the spin state upon surface deposition is challenging.
Lalminthang Kipgen   +14 more
doaj   +1 more source

Pressure and Temperature Sensors Using Two Spin Crossover Materials

open access: yesSensors, 2016
The possibility of a new design concept for dual spin crossover based sensors for concomitant detection of both temperature and pressure is presented. It is conjectured from numerical results obtained by mean field approximation applied to a Ising-like ...
Catalin-Maricel Jureschi   +5 more
doaj   +1 more source

Spin Crossover in New Iron(II) Coordination Compounds with Tris(pyrazol-1-yl)Methane

open access: yesCrystals, 2020
We review here new advances in the synthesis and investigation of iron(II) coordination compounds with tris(pyrazol-1-yl)methane and its derivatives as ligands.
Olga G. Shakirova, Ludmila G. Lavrenova
doaj   +1 more source

Mosaicity of Spin-Crossover Crystals

open access: yesCrystals, 2018
Real crystals are composed of a mosaic of domains whose misalignment is evaluated by their level of “mosaicity” using X-ray diffraction. In thermo-induced spin-crossover compounds, the crystal may be seen as a mixture of metal centres, some ...
Sabine Lakhloufi   +7 more
doaj   +1 more source

Molecular-scale dynamics of light-induced spin cross-over in a two-dimensional layer

open access: yesNature Communications, 2016
Spin crossover molecules may find applications in ultimately small magnetic devices, given the sensitivity of their spin-states to external stimuli. Here, the authors show a light-induced transition between two ordered dynamic phases in two-dimensional ...
Kaushik Bairagi   +15 more
doaj   +1 more source

Synthesis, Crystal Structures and Magnetic Properties of Composites Incorporating an Fe(II) Spin Crossover Complex and Polyoxometalates

open access: yesInorganics, 2017
[Fe(dppOH)2]2+ (dppOH = 2,6-di(pyrazol-1-yl)-4-(hydroxymethyl)pyridine) is known to show spin crossover (SCO) behavior and light-induced excited spin state transitions (LIESST).
Satoshi Kuramochi   +4 more
doaj   +1 more source

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