Results 1 to 10 of about 9,377 (116)
Atomically tweaking spin-crossover cooperativity to augment molecular memory density [PDF]
Spin-crossover complexes are promising candidates for molecular bits owing to their magnetic bistability. However, it’s a formidable challenge to turn densely packed spin-crossover molecules into high-density bits due to cooperative switching dynamics ...
Jing Liu +11 more
doaj +2 more sources
The Influence of the Substrate on the Functionality of Spin Crossover Molecular Materials [PDF]
Spin crossover complexes are a route toward designing molecular devices with a facile readout due to the change in conductance that accompanies the change in spin state.
Saeed Yazdani +4 more
doaj +2 more sources
Cooperative spin crossover leading to bistable and multi-inert system states in an iron(III) complex [PDF]
Cooperativity among spin centres has long been the royal road in spin crossover (SCO) research to impose magnetic bistability in terms of thermal hysteresis.
Andreas Dürrmann +5 more
doaj +2 more sources
Elastocaloric, barocaloric and magnetocaloric effects in spin crossover polymer composite films [PDF]
Giant barocaloric effects were recently reported for spin-crossover materials. The volume change in these materials suggests that the transition can be influenced by uniaxial stress, and give rise to giant elastocaloric properties.
Klara Lünser +10 more
doaj +2 more sources
Coupled spin cross-over and ferroelasticity: revisiting the prototype [Fe(ptz)6](BF4)2 material
Spin-crossover (SCO) materials exhibit thermal conversion from low to high-spin states. We review different models developed to describe this entropy-driven process and the occurrence of cooperative conversions resulting from elastic interactions.
Eric Collet +3 more
doaj +1 more source
Spin-crossover molecules can change their spin-state under a variety of stimuli making them ideal sensors; however, they are typically insulating and unstable.
Julia Villalva +11 more
doaj +1 more source
Controlling the strong light-matter coupling in metal-dielectric optical resonators using spin-crossover molecules [PDF]
We report the observation of (ultra)strong light-matter coupling, in the UV spectral region, between optical modes of a metal/dielectric bilayer nanocavity and the electronic excitations of spin-crossover (SCO) molecules.
Ridier Karl +5 more
doaj +1 more source
Ultrafast spin crossover in a single crystal [PDF]
Femtosecond spectroscopy and electron diffraction are used to characterize spin crossover in single crystal iron(II)-tris(bipyridine)-bis(hexafluorophosphate). The high-spin lifetime is reduced compared to in solution.
Field Ryan L. +5 more
doaj +1 more source
In real materials, a spin quantum number assumes a fixed value, which makes it challenging to realize a crossover between quantum and classical spin regimes.
Daisuke Yamamoto +6 more
doaj +1 more source
Here, we examine the conductance changes associated with the change in spin state in a variety of different structures, using the example of the spin crossover complex [Fe(H2B(pz)2)2(bipy)] (pz = (pyrazol-1-yl)-borate and bipy = 2,2′-bipyridine) and [Fe ...
M. Zaid Zaz +3 more
doaj +1 more source

