Results 81 to 90 of about 1,420 (210)

Redefining the Nitrogen Cycle Through Electronic Configuration Driven Electrocatalysis for Low Carbon Energy

Carbon Energy, EarlyView.
This review reveals how electronic configuration engineering governs the entire electrocatalytic nitrogen cycle, providing structure‐informed insights into reaction selectivity, catalytic durability, and sustainable nitrogen utilization across energy and environmental systems. ABSTRACT The global nitrogen cycle is essential to food production, chemical
Jiamu Feng, Linai Zhou, Mincan Yang, Aoxiang Zhu, Zengfeng Wei, Weilin Xu, Jia Li, Jun Wan   +7 more
wiley   +1 more source

Oxidation of Allylic Alcohols by Manganese Oxides: Elucidating the Influences of MnOx Structure and Mn Oxidation State on Reactivity

Chemistry – A European Journal, EarlyView.
Manganese oxides (MnOX) of different structures and with different Mn oxidation states exhibit significant variation in their reactivity toward the oxidation of allylic alcohols. Using two allylic alcohol model substrates, we demonstrate the relationship between activity and MnOX structure, Mn4+ content and incorporated secondary cations.
Erdogan Kasisari, Leandra Meyer, S. Esmael Balaghi, Harald Scherer, Patrick Elsässer, Anna Fischer, Philipp Kurz   +6 more
wiley   +1 more source

A study of Ni‐Co/CeO2 catalyst derived from metal–organic framework for dry reforming of methane

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract The efficacy of cobalt‐doped, MOF‐derived catalysts for dry reforming of methane (DRM) was examined. The focus was on the influence of varying nickel and cobalt molar ratios on catalytic performance. Three catalysts with Ni:Co ratios of 1:1, 1:0.5, and 0.5:1, were synthesized and tested with cerium oxide as a constant support. The DRM reaction
Ruth D. Alli, Nader Mahinpey
wiley   +1 more source

Green and sustainable synthesis of magnetite from copper slag via citrate complexation for methylene blue dye removal from water

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract This study proposes a novel, green, and sustainable method for synthesizing magnetic iron oxides from metallurgical copper slag (CS), leveraging its iron content as a valuable resource. Iron was extracted via acid leaching using edible citric acid (ECA), forming a citrate–iron complex (CSL), which was subsequently thermally decomposed at 300°C
Melisa Portilla‐Sangabriel, Karen Valencia García, Tania‐Ariadna García‐Mejía, Agileo Hernández‐Gordillo, Rosa‐María Ramírez‐Zamora   +4 more
wiley   +1 more source

Experimental methods in chemical engineering: Magnetometry

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Magnetometry is a non‐invasive technique to characterize the behaviour of magnetic materials of which the most common contain Fe, Co, and Ni. Vibrating sample magnetometers (VSMs) vibrate samples at a fixed frequency in a static, homogeneous magnetic field to induce a voltage in pick up coils according to Faraday's law of induction.
Michael Claeys, Dominic De Oliveira, Gregory S. Patience, M. Olga Guerrero‐Pérez   +3 more
wiley   +1 more source

Role of Lewis centres on ethanol dehydrogenation over the Cu‐Cr/γ‐Al2O3 system

The Canadian Journal of Chemical Engineering, EarlyView.
Cu–Cr interactions on alumina enhance Lewis acid site density, boosting selectivity towards ethanol dehydrogenation products. Soft coke formation on copper and Cu–Cr sites drives deactivation, shifting the reaction towards unwanted dehydration products.
Sakun Preedavijitkul, Wei Tian, Andres Rodriguez‐Marmolejo, Pantita Trongjitraksa, Chaowat Autthanit, Piyasan Praserthdam, Bunjerd Jongsomjit, Jose E. Herrera   +7 more
wiley   +1 more source

Experimental methods in chemical engineering: Temperature‐programmed oxidation—TPO

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Temperature‐programmed oxidation (TPO) probes the oxidative capacity and redox properties of solid materials—catalysts, metal oxides, perovskites, and carbonaceous deposits. It identifies coke type, distribution, and reactivity. TPO instruments pass an oxidizing gas (diluted O2$$ {\mathrm{O}}_2 $$, air, or less commonly N2O$$ {\mathrm{N}}_2 ...
Gholamreza Roohollahi, Jildimara de Jesus Santana, Alexander R. P. Harrison, Sara Andreoli, Ewa Marek, Stuart Scott, Mohammad Latifi, Gregory S. Patience   +7 more
wiley   +1 more source

Tailored ozone activation on geometrical-site-dependent cobalt with selective coordination. [PDF]

Nat Commun
Liu S, Wang Y, Liu Y, Chen P, Kong T, Duan X, Chen C, Sun H, Wang S.   +8 more
europepmc   +1 more source

Going from Pt to PGM‐free Catalysts: Effects of Ink Compositions on PEM Water Electrolysis

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Optimisation of cathode ink formulations regarding the ratio between catalyst, carbon and binder results in a boost in PEM water electrolysis performance. The optimisation can be transferred from pentlandites to platinum and selenide catalysts, wherein the metal chalcogenides show a stronger performance enhancement.
Janna Wierper, Jannick Hiltrop, Kevinjeorjios Pellumbi, Julia Jökel, Sebastian Sanden, Miłosz Kożusznik, Andrzej Mikuła, Ulf‐Peter Apfel   +7 more
wiley   +1 more source

Half-metallic ferromagnetism and thermoelectric-efficient behavior in chalcogenide spinels MgNi₂X₄ (X = S, Se): a first-principles approach. [PDF]

RSC Adv
Ramzan A, Sofi MY, Ishfaq-Ul-Islam M, Khan MS, Khan MA.   +4 more
europepmc   +1 more source