Results 71 to 80 of about 11,270 (260)

Rapidly Diversifying Hydrogen‐Bonded Organic Frameworks With Permanent Porosity

open access: yesAngewandte Chemie, EarlyView.
This article reviews diversifying hydrogen‐bonded organic frameworks (HOFs) with permanent porosity reported over the past 15 years, based on the molecular structures of their constituent tectons. Furthermore, several distinctive aspects and concepts are described, such as permanent porosity, isostructural (isoreticular) HOFs, and multicomponent mixed ...
Taito Hashimoto, Ichiro Hisaki
wiley   +2 more sources

Lattice Coherency‐Driven (111)‐Oriented Wide Bandgap Perovskite Films

open access: yesAdvanced Energy Materials, EarlyView.
Methylammonium lead chloride (MAPbCl3)‐derived seed templates regulate wide‐bandgap perovskite crystallization through coupled thermodynamic and kinetic effects. Lattice‐coherent templating lowers the energy cost for (111) epilayer growth, while growth retardation controls crystallization kinetics, ultimately producing highly crystalline face‐up (111 ...
Yu‐Na Lee   +5 more
wiley   +1 more source

High‐Performance Noble‐Metal‐Free Perovskite Solar Cells Enabled by MoOX/Cr/Al Multilayer Electrodes

open access: yesAdvanced Energy Materials, EarlyView.
Cost‐effective perovskite solar cells (PSCs) are developed using a noble‐metal‐free MoOX/Cr/Al multilayer electrode. The devices achieve a power conversion efficiency (PCE) of 25.6%, competitive with that of Au‐based devices (26.3%), and a 25.5 cm2 mini‐module shows 21.3% PCE.
Wooyeon Kim   +7 more
wiley   +1 more source

Stereoselective Transformation of Cyclodecene-1,4-dione Systems, Derived from Steroids, to the Corresponding spiro-γ-lactones. A Semiempirical MO Study

open access: yesMolecules, 1999
The thermal and acid-catalyzed intramolecular rearrangement of the (Z)- and (E)-cyclodecene-1,4-dione compounds deriving from steroids, 2a,b and 3a,b, respectively, proceeds stereoselectively to give the corresponding configurationally different spiro ...
Milan Dabovich   +6 more
doaj   +1 more source

Verification and Mitigation of Proton‐Induced Non‐Ionizing Damage in Perovskite Solar Cells for Space Applications

open access: yesAdvanced Energy Materials, EarlyView.
Metal‐halide perovskite solar cells offer high‐efficiency power for orbital missions but suffer from permanent proton‐induced degradation. This work identifies non‐ionizing energy loss (NIEL) as the primary driver of irreversible failure, inducing atomic displacements and microcracks in the high‐fluence regime. Through energy‐tuned mapping and scalable
Jangwon Byun   +10 more
wiley   +1 more source

Entry to new spiroheterocycles via tandem Rh(II)-catalyzed O–H insertion/base-promoted cyclization involving diazoarylidene succinimides

open access: yesBeilstein Journal of Organic Chemistry
A facile approach to novel medicinally relevant spiro heterocyclic scaffolds (namely furan-2(5H)-ones, tetrahydrofurans and pyrans spiro-conjugated with the succinimide ring) has been developed.
Alexander Yanovich   +4 more
doaj   +1 more source

Chiral Molecular Configuration‐Mediated Crystallization of Perovskites for High‐Performance Solar Cells

open access: yesAdvanced Energy Materials, EarlyView.
In this work, we propose a chiral stereo‐anchoring strategy to modulate the colloidal evolution and crystallization behavior of FAPbI3 perovskites via stereochemical molecular design, which effectively regulates nucleation kinetics and promotes ordered crystal growth.
Runkang Wang   +14 more
wiley   +1 more source

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