Localization of Spiropyran Activation
Functionalization of planar and curved glass surfaces with spiropyran (SP) molecules and localized UV-induced activation of the mechanophore are demonstrated. Fluorescence spectra of UV-irradiated SP-functionalized surfaces reveal that increases in surface roughness or curvature produce more efficient conversion of the mechanophore to the open ...
Martha E. Grady +5 more
openaire +2 more sources
Two-photon photopolymerization directly initiated by spiropyran photochromic molecules
Here, we report the ability of spiropyrans to initiate two-photon polymerization (TPP) for the first time in the literature. The comparison and synergies between the spiropyran photochromic molecule of interest, namely 6-nitro-BIPS, and well-known ...
Dandan Ge +7 more
doaj +1 more source
Double-stranded RNA induction asa potential dynamic biomarkerfor DNA-demethylating agents
Hypomethylating agents (HMAs), such as azacitidine and decitabine, induce cancer cell death by demethylating DNAs to promote the expression of tumor-suppressor genes. HMAs also reactivate the transcription of endogenous double-stranded RNAs (dsRNAs) that
Minjeong Kang +14 more
doaj +1 more source
A divergent asymmetric approach to aza-spiropyran derivative and (1S,8aR)-1-hydroxyindolizidine
BackgroundSpiroketals and the corresponding aza-spiroketals are the structural features found in a number of bioactive natural products, and in compounds possessing photochromic properties for use in the area of photochemical erasable memory, self ...
Jian-Feng Zheng +4 more
doaj +1 more source
Photochromic spiropyran monolithic polymers: Molecular photo-controllable electroosmotic pumps for micro-fluidic devices [PDF]
A novel photo-controllable micro-fluidic electroosmotic pump based on spiropyran monolithic polymers is presented here for the first time. Photochromic monolithic scaffolds have been synthesised within poly(tetrafluoroethylene) coated fused silica ...
Abele, Silvija +9 more
core +1 more source
Photoswitchable Spiropyran Dyads for Biological Imaging [PDF]
The synthesis of a small-molecule dyad consisting of a far-red-emitting silicon rhodamine dye that is covalently linked to a photochromic spironaphthothiopyran unit, which serves as a photoswitchable quencher, is reported. This system can be switched reversibly between the fluorescent and nonfluorescent states using visible light at wavelengths of 405 ...
Xiong Y +5 more
openaire +3 more sources
Solid state photochromism of spiropyrans
A series of spiropyrans possessing photochromic properties in solid state were investigated. UV irradiation (λmax=365 nm) of the thin vacuum deposited spiropyran films results in conversion of the colorless form to the photocolored one.
B. S. Lukyanov +7 more
doaj +1 more source
Investigating nano-structuring within imidazolium ionic liquids: A thermodynamic study using photochromic molecular probes [PDF]
Following previous studies involving the thermal relaxation of spirocyclic compounds we extended our studies to investigate the formation of nano-structured domains in ionic liquids (ILs).
Byrne, Robert +3 more
core +1 more source
Spiropyran as a potential molecular diagnostic tool for double-stranded RNA detection
Background Long double-stranded RNAs (dsRNAs) are duplex RNAs that can induce immune response when present in mammalian cells. These RNAs are historically associated with viral replication, but recent evidence suggests that human cells naturally encode ...
Ahsan Ausaf Ali +3 more
doaj +1 more source
Synthesis of novel silica encapsulated spiropyran-based thermochromic materials
A series of novel spiropyrans were synthesized through the condensation of substituted 3,3-dimethyl-2-methyleneindoline with different nitro-substituted o-hydroxy aromatic aldehydes. Indoles were initially substituted with a variety of alkanes and esters
Anila Iqbal +4 more
doaj +1 more source

