Overcrowded Alkene Photo‐Redox‐Switches Based on Quinolinium/Carbene Building Blocks
A modular synthesis of a new class of photo‐ and redox‐switches is described based on the combination of quinolinium salts and carbenes. Photochemical switching allows to selectively switch between folded E/Z isomers, while electrochemical switching allows to change between neutral, radical cation and dicationic oxidation states, which are all isolable
Chris Burdenski +10 more
wiley +1 more source
Decoding structural rigidity and charge-transfer polarization in barbituric-acid-based donor-π-acceptor chromophores. [PDF]
Miryala K, Katdare M, Dey N.
europepmc +1 more source
Surface Charges Guided Quasi‐TEM‐mode Microwave Propagation along Dielectric Nanowire
According to Maxwell's equations, a single‐conductor transmission line cannot allow TEM‐mode electromagnetic wave propagation, however, this is based upon the assumption that dielectric material is isolated from the environment. In practice, surface electrostatic charges widely existed in nano‐materials with large surface‐to‐volume ratio.
BoYan Xu +7 more
wiley +1 more source
Evaluating Antibody Quality via Simultaneous Size and Charge Measurement with Single Protein Oscillators. [PDF]
Jia R +12 more
europepmc +1 more source
ABSTRACT We introduce a family of bosonic quantum error‐correcting codes built as a rotation‐symmetric superposition of squeezed vacuum states, which promise protection against both loss and dephasing noise channels. The robustness of these “squeezed‐vacuum codes” arises from being arranged at evenly spaced angles in phase‐space, and simultaneously in ...
Nir Gutman +4 more
wiley +1 more source
Active compensation of the AC Stark shift in a two-photon rubidium optical frequency reference using power modulation. [PDF]
Andeweg Y, Kitching J, Hummon MT.
europepmc +1 more source
Patterns of spinal motion, kinematic spaces and the land‐to‐sea transition in carnivorans
Using 3D reconstructions, we quantify intervertebral joint mobility to investigate how cervical, thoracic, and lumbar vertebral regions evolved distinct kinematic roles in pinnipeds. The findings reveal lineage‐specific adaptations for swimming and highlight the functional significance of vertebral joint flexibility in ecological transitions.
Juan Miguel Esteban +3 more
wiley +1 more source
Stabilizing Ultrathin CsPbBr<sub>3</sub> Nanoplatelet Films for Deterministic Strong Light-Matter Coupling. [PDF]
Odewale EO, Boateng ID, Rury AS.
europepmc +1 more source
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +1 more source
High-Precision Time Synchronization and Autonomous Maintenance for LEO Satellite Constellations Based on High-Stability Crystal Oscillators. [PDF]
Mu L, Hu X, Wu M, Li J.
europepmc +1 more source

