Results 181 to 190 of about 3,681,214 (292)

Cobalt‐Catalyzed C─N Bond Formation via Metal‐Hydride Hydrogen Atom Transfer (MHAT)

open access: yesAngewandte Chemie, EarlyView.
Cobalt‐catalyzed metal‐hydride hydrogen atom transfer (Co‐MHAT) converts simple alkenes into C─N bonds under mild, near‐neutral conditions. A shared Co─H‐initiated radical/organocobalt intermediate is channeled into radical trapping, radical‐polar crossover, or radical ligand transfer, unifying hydroamination, hydroazidation, hydroamidation, and remote
Arman Khosravi, Ming‐Yu Ngai
wiley   +1 more source

Methane Activation by B5+ Toward a CB5H2+ Isomer Containing a Planar Tetracoordinate Carbon Atom

open access: yesAngewandte Chemie, EarlyView.
Methane activation by B5+ yields CB5H2+ through H2 elimination. Electronic‐structure calculations connect the nascent dehydrogenation product to a low‐lying isomer containing a planar tetracoordinate carbon atom. ABSTRACT Planar tetracoordinate carbon (ptC) motifs have been identified predominantly in the global‐minimum structures of gas‐phase clusters
Qin‐Wei Zhang   +11 more
wiley   +1 more source

Chiral Fjord‐Edged Nanographenes Constructed by Allylic‐Migration‐Mediated Cyclization

open access: yesAngewandte Chemie, EarlyView.
A novel allylic‐migration‐mediated cyclization strategy enables the construction of two fjord‐edged nanographenes without steric blocking groups. The resulting non‐planar molecules exhibit remarkable chiroptical properties, with an absorption dissymmetry factor surpassing those of pristine [5]helicene and previously reported fjord‐edged nanographenes ...
Zhen‐Lin Qiu   +7 more
wiley   +1 more source

Hydration‐Gated Photoinduced Electron Transfer in BODIPY Dyes

open access: yesAngewandte Chemie, EarlyView.
Hydration switches photoinduced electron transfer (PET) ON in alkoxy‐coordinated BODIPY dyes via specific hydrogen bonding. This gating yields a fluorescence lifetime span of ∼6 ns, enabling fluorescence lifetime imaging microscopy (FLIM) contrast in live cells and organoids. ABSTRACT Fluorescent probes based on photoinduced electron transfer (PET) are
Venkata N. K. Mamillapalli   +9 more
wiley   +1 more source

Maximum water stress is decoupled from climate, traits, and growth in a xeric oak. [PDF]

open access: yesNew Phytol
Anderegg LDL   +7 more
europepmc   +1 more source

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