Results 181 to 190 of about 4,516,287 (245)

Key Drivers of Activity and Selectivity in Cu‐Based Catalysts for Methanol Synthesis From CO2: Insights From Atomically Dispersed Promoters

Angewandte Chemie, EarlyView.
Mechanistic studies on model Cu─M/SiO2 catalysts (M = Zn, Ga, and In) reveal that promoters enable a formate spillover pathway from Cu to Mn+ (n = 2 or 3) sites. The promoter's electronic effect on formate bond strengths serves as a quantitative descriptor for activity and selectivity, balancing spillover dynamics with intermediate stabilization to ...
Nat Phongprueksathat, Gina Noh, Scott R. Docherty, Damian Vico van Berkel, Yannik Stiefel, Christophe Copéret, Atsushi Urakawa   +6 more
wiley   +1 more source

Exclusive Hydroformylation of Terminal Olefins: A Phosphorus‐Free Ruthenium System for the Selective Functionalization of Complex Mixtures

Angewandte Chemie, EarlyView.
Development of a phosphorus‐free Ru/DBU catalyst enabling highly chemo‐ and regioselective hydroformylation of terminal olefins, sparing internal double bonds. Optimization of reaction parameters, ligand effects, and substrate scope including industrial feedstocks was realized.
Mohamed Niyaz Vellala Syed Ali, Ida Ziccarelli, Dilver Peña Fuentes, Christoph Kubis, Robert Franke, Ralf Jackstell, Matthias Beller   +6 more
wiley   +1 more source

Chiral Fjord‐Edged Nanographenes Constructed by Allylic‐Migration‐Mediated Cyclization

Angewandte Chemie, EarlyView.
A novel allylic‐migration‐mediated cyclization strategy enables the construction of two fjord‐edged nanographenes without steric blocking groups. The resulting non‐planar molecules exhibit remarkable chiroptical properties, with an absorption dissymmetry factor surpassing those of pristine [5]helicene and previously reported fjord‐edged nanographenes ...
Zhen‐Lin Qiu, Jiang‐Feng Xing, Boris Borrisov, Qing‐Song Deng, Renxiang Liu, Muhammad Imran, Ji Ma, Xinliang Feng   +7 more
wiley   +1 more source

Pt‐Mediated Co‐Adsorption of Hydroxyl and Nitrogen‐Heterocyclic Species Over Cu/CuO Heterostructure Enhances Coupled Azotriazole Electrosynthesis and Dual‐Electrode Hydrogen Production

Angewandte Chemie, EarlyView.
Pt@Cu/CuO heterostructures were designed for electrochemical N─N coupling of 3,5‐diamino‐1H‐1,2,4‐triazole. Mechanism investigation revealed that the Pt sites mediated co‐adsorption of substrates and hydroxyl on Cu/CuO sites. The elaborate Pt@Cu/CuO achieved an ultralow working potential of 0.832 VRHE with a high FE of 95%. A long‐term stability of 600
Jiachen Li, Hanggu Su, Yuqiang Ma, Meng Li, Ruhao Zhang, Cihang Wang, Zihang Zhao, Jun Hu, Xiaogang Mu, Xuanjun Wang, Haixia Ma, Zhengxiao Guo   +11 more
wiley   +1 more source

Elucidating Photo‐Kinetic Control in Photothermal Reverse Water‐Gas Shift Reaction

Angewandte Chemie, EarlyView.
Light directly regulates the rate‐determining step (RDS) in photothermal catalysis. In a Mars–van Krevelen (MvK)‐type reverse water‐gas shift (RWGS) reaction over In‐doped MoO2, light shifts the RDS from the H2‐related reduction half‐reaction to the CO2‐related oxidation half‐reaction, enhancing catalytic activity and lowering the apparent activation ...
Junchuan Sun, Rui Song, Chang Xu, Xue Ding, Wanguo Gao, Athanasios A. Tountas, Zhe Lu, Jiakun Wang, Zeshu Zhang, Xiaolu Zhuo, Yingfang Yao, Zhigang Zou, Geoffrey A. Ozin, Lu Wang   +13 more
wiley   +1 more source

Farnesyltransferase Enables Modular Assembly of Dual‐Functional Nanobody Conjugates for in Vivo Imaging of Inflammation

Angewandte Chemie, EarlyView.
A modular farnesyltransferase‐based chemoenzymatic platform enables fast, site‐specific labeling of nanobodies for PET imaging of inflammation. CD11b‐targeted PET agents selectively image myeloid‐driven inflammation, while CD45‐targeted PET agents provide sensitive whole‐body immune mapping.
Sneha Venkatachalapathy, Yoon Ho Lee, Ali Salehi Farid, Heydar Moravej, Sina Djafari Rouhani, Jennifer E. Rowley, Mohammad Rashidian, Mark D. Distefano   +7 more
wiley   +1 more source

Engineering Atomically Precise Cu4I4 Nanoclusters With Integrated Adsorption and Hydrogenation Functions for Efficient Photocatalytic Nitrate‐to‐Ammonia Conversion

Angewandte Chemie, EarlyView.
Efficient photocatalytic nitrate‐to‐ammonia conversion is achieved over an atomically precise Cu4I4 motif through dual‐site cooperation. Lewis‐acidic Cu centers promote nitrate adsorption and activation, while adjacent I sites facilitate active hydrogen generation for stepwise hydrogenation.
Wanting Zhang, Yuehua Li, Junjie Jin, Chunwei Dong, Xi Cao, Xingchi Li, Xuanjun Wu, Jiaqi Wang, Atta Ullah, Gaspar Ferreyra Vaggione, Rodrigo A. Iglesias, Yun Chen, Emiliano Cortés, Dengsong Zhang   +13 more
wiley   +1 more source

Fluorescent cAMP Analogs: Enzymatic Synthesis, Unexpected Photophysical Behavior and Protein Kinase A Recognition

Angewandte Chemie, EarlyView.
Cyclic adenosine monophosphate (cAMP) is a key cellular second messenger. Adenylyl cyclase converts emissive isomorphic nucleoside triphosphates into fluorescent cAMPs. cthAMP displays unusually high brightness compared to thATP, its precursor, enabling real‐time monitoring of enzymatic reactions.
Deyuan Cong, Victor Dubois, Jamie Y. Lam, Yitzhak Tor   +3 more
wiley   +1 more source

Stable isotope ratio analysis for authentication of chitosan

, 2018
Perini, M., Nardin, T., Venturelli, M., Pianezze, S., Larcher, R.   +4 more
openaire   +1 more source

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Stable isotope ratio profiling of testosterone preparations

Drug Testing and Analysis, 2010
AbstractGas chromatography‐combustion‐isotope ratio mass spectrometry (GC‐C‐IRMS) is the preferred method of confirming the administration of exogenous testosterone by athletes. This relies on synthetic testosterone preparations being depleted in 13C compared to natural testosterone.
Adam, Cawley, Michael, Collins, Rymantas, Kazlauskas, David J, Handelsman, Robert, Heywood, Mitchell, Longworth, Andrea, Arenas-Queralt   +6 more
openaire   +2 more sources