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Updated Stagnation Point Aeroheating Correlations for Mars Entry [PDF]

open access: yes
The objective of this work was to develop new engineering correlations for stagnation point aeroheating for Mars entry vehicles. New convective and radiative heating relations have been formulated over a wide range of entry conditions.
Brandis, A. M.
core   +1 more source

Plastics of the Future? Interdisciplinary Review on Biobased and Biodegradable Polymers: Progress in Chemistry, Societal Views, and Environmental Implications

open access: yesAngewandte Chemie International Edition, Accepted Article.
Global demand to reduce polymer waste and microplastics pollution has increased in recent years, prompting further research, development, and wider use of biodegradable and biobased polymers (BBPs). BBPs have emerged as promising alternatives to conventional plastics, with the potential to mitigate the environmental burdens of persistent plastic waste.
Sara T. R. Velasquez   +5 more
wiley   +1 more source

Influence of Ligand Design and Non‐Covalent Interactions on the Isoselective Ring‐Opening Polymerization of rac‐ß‐Butyrolactone using Salan and Salalen Rare‐Earth Metal Catalysts

open access: yesAngewandte Chemie International Edition, Accepted Article.
We herein report the influence of the ligand framework on the isoselective ring‐opening polymerization (ROP) of rac‐β‐butyrolactone using highly active in situ generated salan [ONNO]H2 and salalen [ONNO]H rare‐earth metal complexes. The stereochemistry was found to be highly dependent on the ortho‐substituents, enabling the synthesis of either ...
Stefanie Hörl   +4 more
wiley   +1 more source

Long‐Lasting Hydrophilicity Induced by Ultraviolet Light on Surface Modified Hydrophobic Polylactic Acid

open access: yesJournal of Applied Polymer Science, EarlyView.
In light of increasing applications of compostable materials, surface treatment on PLA to increase roughness and hydrophobicity has been investigated. However, modifying wettability might hinder degradation. UVC exposure has significant effects on the wettability of textured PLA substrates, allowing a complete wettability switch due to chain scission ...
William Simon   +8 more
wiley   +1 more source

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