Results 261 to 270 of about 513,877 (318)

A criterion based on computational singular perturbation for the identification of quasi steady state species: A reduced mechanism for methane oxidation with NO chemistry

open access: closedCombustion and Flame, 2008
A criterion based on computational singular perturbation (CSP) is proposed to effectively distinguish the quasi steady state (QSS) species from the fast species induced by reactions in partial equilibrium. Together with the method of directed relation graph (DRG), it was applied to the reduction of GRI-Mech 3.0 for methane oxidation, leading to the ...
Tianfeng Lu, Chung K. Law
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Chemistry and Transport of Potassium during the Non‐Steady State of Syenite Leaching

open access: closedSoil Science Society of America Journal, 2017
Core Ideas A flow system for the release and extraction kinetics of ions from a rock fertilizer. The initial release of ions from syenite studied using ICP‐MS and a pH meter. Fast surface potassium–proton ion exchange and K desorption observed. Syenite is mainly composed of potassium feldspar (Kfs), which is a structural K‐bearing mineral in soil ...
Kejing Li, Christi A. Dawydiak
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An efficient Chebyshev wavelet based analytical algorithm to steady state reaction–diffusion models arising in mathematical chemistry [PDF]

open access: closedJournal of Mathematical Chemistry, 2015
A mathematical model of amperometric biosensors has been developed. The model is based on non-stationary diffusion equation containing a nonlinear term related to non-Michaelis–Menten kinetics of the reaction. In this paper, an efficient Chebyshev wavelet based approximation method is introduced for solving the steady state reaction–diffusion equations.
M. Mahalakshmi, G. Hariharan
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Study of the chemistry of NH3 on aluminum nitride and oxynitride under steady-state conditions using external-reflection infrared spectroscopy

open access: closedThin Solid Films, 1999
Abstract Polarization-modulated Fourier-transform infrared reflection absorption spectroscopy has been applied to the characterization of thin films of AlN and Al oxynitride (‘AlON’) on NiAl(111) and to the observation of surface chemical processes under steady-state conditions in a static NH 3 ambient of up to 200 Torr.
V. M. Bermudez
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An Efficient Wavelet Based Approximation Method to Steady State Reaction–Diffusion Model Arising in Mathematical Chemistry

open access: closedThe Journal of Membrane Biology, 2014
The mathematical model of Rahamathunissa and Rajendran (J Math Chem 44:849-861, 2008) in an amperometric biosensor response is discussed. In this paper, we have applied the shifted second kind Chebyshev wavelets (CW) to obtain the numerical solutions of reaction-diffusion equations containing a nonlinear term related to Michaelis-Menton kinetics of the
M. Mahalakshmi, G. Hariharan
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Cellular titration of apoptosis with steady state concentrations of H2O2: submicromolar levels of H2O2 induce apoptosis through fenton chemistry independent of the cellular thiol state

open access: closedFree Radical Biology and Medicine, 2001
Apoptosis was studied under conditions that mimic the steady state of H(2)O(2) in vivo. This is at variance with previous studies involving a bolus addition of H(2)O(2), a procedure that disrupts the cellular homeostasis. The results allowed us to define three phases for H(2)O(2)-induced apoptosis in Jurkat T-cells with reference to cytosolic steady ...
Fernando Antunes, Enrique Cadenas
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Critical loads of acidity for surface waters in south-central Ontario, Canada: regional application of the Steady-State Water Chemistry (SSWC) model

open access: closedCanadian Journal of Fisheries and Aquatic Sciences, 2002
Critical loads of acidity and the amount by which these critical loads are exceeded by atmospheric deposition (termed "exceedances") were estimated for 1469 lakes from five regions in south-central Ontario, Canada, using single lake chemistry measurements and sulphur deposition data for the period 1976–1999.
A. Henriksen   +2 more
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Testing the steady-state water chemistry model predictions of pre-industrial lake pH with paleolimnological data from northern Sweden☆

open access: closedScience of The Total Environment, 2008
Criteria are needed for distinguishing naturally acid water from that acidified by air pollution, especially in the organic-rich waters of northern Sweden. The Steady-State Water Chemistry Model (SSWC) was augmented to include organic acidity so that it could predict pre-industrial pH in organic-rich waters.
Kevin Bishop   +3 more
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Free Radical Addition Polymerization Kinetics without Steady-State Approximations: A Numerical Analysis for the Polymer, Physical, or Advanced Organic Chemistry Course

open access: closedJournal of Chemical Education, 2014
A numerical analysis of the free radical addition polymerization system is described that provides those teaching polymer, physical, or advanced organic chemistry courses the opportunity to introduce students to numerical methods in the context of a simple but mathematically stiff chemical kinetic system.
H. Darrell Iler   +4 more
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Steady state approximations and urban atmospheric chemistry

open access: closedThe Journal of Physical Chemistry, 1977
L. A. Farrow, T. E. Graedel
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