Breaking Trade-Off between Selectivity and Activity of Nickel-Based Hydrogenation Catalysts by Tuning Both Steric Effect and d-Band Center. [PDF]
Adv Sci (Weinh), 2019 Gao R +6 more
europepmc +1 more source
Spatial‐Compatibility‐Assisted Molecular Intercalation in MXenes
Advanced Materials, EarlyView.This work demonstrates a solvent–free NH4F–mediated route for simultaneous Al removal and molecular intercalation in MXenes. Intercalants are selected by comparing their crystallographic X, Y, and Z dimensions with the MXene interlayer spacing, establishing a spatial‐compatibility criterion that rationalizes guest–host matching and enables predictive ...
Minhao Sheng +6 more
wiley +1 more source
Poly(Alkoxythiophene) Rod‐Coil Block Copolymers for Organic Electrochemical Transistors
Advanced Materials, EarlyView.We present the first synthesis of poly(3‐alkoxythiophene) rod‐coil block copolymers as a new architecture for OMIECs. Incorporating PEG and PLLA coils can enhance device performance beyond the homopolymer. The figure‐of‐merit depends uniquely on coil length.
Junfu Tian +23 more
wiley +1 more source
Bulletin of the Chemical Society of Ethiopia, 2009 The aim of this research is to determine the possible solar energy storage in the norbornadiene (1) / quadricyclane (2) system, through involving steric effects on various position of carbon C1, C2 or C7 for 1 and 2; calculating the corresponding ...
E. Vessally
doaj
Single‐Particle FRET Probes Heterogeneity in the Ligand Shell of Colloidal Perovskite Quantum Dots
Advanced Materials, EarlyView.Single‐particle, single‐molecule Förster resonance energy transfer turns dye‐tagged ligands into nanorulers for the otherwise elusive organic shell of CsPbBr3 quantum dots. Distance variations within individual particles reveal pronounced local heterogeneity, while changes in the surrounding ligand chemistry shift the average dye–surface separation ...
Leon G. Feld +6 more
wiley +1 more source
Advanced Materials, EarlyView.In the proposed model, a photoinduced nanoreactor uses Cu2O self‐photooxidation to generate localized supersaturation. A metastable supersaturation state first forms a shell, creating a spatially confined environment that restricts reactant exchange; continued Cu release then drives the local environment toward a labile regime that favors predominantly
Yongdeok Ahn +5 more
wiley +1 more source
Quantitative Analysis of the Steric Effect in Phosphinophenolate Nickel Catalysts for Ethylene Polymerization. [PDF]
Polym Sci TechnolZheng J +6 more
europepmc +1 more source
Multi‐Li+ Coordination for Superior Room‐Temperature Ionic Conductivity in PEO Solid Electrolytes
Advanced Materials, EarlyView.A phosphonate‐functionalized polycarboxylate ether (P‐PCE) is introduced into PEO electrolytes to induce multi‐Li+ ions coordination, which effectively dissociates lithium salts, liberates Li+ from the strong chelation by PEO chains, and promotes fast Li+ hopping between adjacent coordination sites. Simultaneously, this design establishes dynamic, high‐
Hengming Yan +11 more
wiley +1 more source
Steric Effect-Controlled Atomic Passivation of Colloidal InAs Quantum Dots for Infrared Photodetectors. [PDF]
SmallLee IS +8 more
europepmc +1 more source
Strong Fully Reprocessable Engineered Wood Composites
Advanced Materials, EarlyView.Engineering a hyperbranched adhesive with complementary imine‐bond and hydrogen‐bond networks, combining it with wood particles to fabricate the wood composite (WP/HTP) under mild hot‐pressing conditions. The WP/HTP exhibits 100% mechanical strength recovery after three cycles of reprocessing, and the reprocessed modulus of rupture (MOR) and modulus of
Xilin Zhang +9 more
wiley +1 more source