Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials
Advanced Materials, EarlyView.A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella +3 more
wiley +1 more source
In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts
Advanced Materials, EarlyView.An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea +9 more
wiley +1 more source
Advanced Materials, EarlyView.Structural water is harnessed as an active co‐monomer to drive supramolecular polymerization in bulk water. Zinc(II) Salphen complexes confine water molecules to form hollow, metal–organic nanofibers that assemble into adaptive hydrogels with thermoresponsive mechanics and selective chiral recognition.
Merlin R. Stühler +10 more
wiley +1 more source
Positively Charged Polymer‐Brush MOFs for Large‐Area, Pressure‐Resistant Gas Separation Membranes
Advanced Materials, EarlyView.A universal POPA strategy enables positively charged polymer‐brush MOFs with self‐adaptive interfacial interlocking to resist aggregation under fast processing. This design ensures seamless dispersion within large‐area selective layers, achieving 1 m‐wide roll‐to‐roll fabrication of pressure‐resistant MMCMs with tunable CO2 separation performance ...
Yi Yang +11 more
wiley +1 more source
Beyond the two-conformer model: boat conformers provide stereoselectivity in S<sub>N</sub>1-type glycosylations of <i>manno</i>-type donors. [PDF]
Chem SciRemmerswaal WA +5 more
europepmc +1 more source
Advanced Materials, EarlyView.This review highlights the role of self‐assembled monolayers (SAMs) in perovskite solar cells, covering molecular engineering, multifunctional interface regulation, machine learning (ML) accelerated discovery, advanced device architectures, and pathways toward scalable fabrication and commercialization for high‐efficiency and stable single‐junction and
Asmat Ullah, Ying Luo, Stefaan De Wolf
wiley +1 more source
Flexible Morphology-Controlled Preparation of α‑Calcium Sulfate Hemihydrate from FGD Gypsum in Ethylene Glycol Water Solutions. [PDF]
ACS OmegaGao X +9 more
europepmc +1 more source
Ligand‐Mediated Surface Carrier Modulation in Perovskite Nanocrystals for Charge‐Symmetric LEDs
Advanced Materials, EarlyView.A hydrolysis‐assisted ligand exchange strategy enables surface carrier modulation of perovskite nanocrystals using a multifunctional π‐conjugated ligand. This molecular surface design achieves charge balance and recombination‐zone symmetry in light‐emitting diodes (LEDs), which leads to high‐efficiency perovskite LEDs and establishes a general platform
Jongho Park +11 more
wiley +1 more source
Conformational analysis of difluoromethylornithine: factors influencing its gas-phase and bioactive conformations. [PDF]
Beilstein J Org ChemFreitas MP.
europepmc +1 more source
All‐Optical Reconfigurable Physical Unclonable Function for Sustainable Security
Advanced Materials, EarlyView.An all‐optical reconfigurable physical unclonable function (PUF) is demonstrated using plasmonic coupling–induced sintering of optically trapped gold nanoparticles, where Brownian motion serves as a robust entropy source. The resulting optical PUF exhibits high encoding density, strong resistance to modeling attacks, and practical authentication ...
Jang‐Kyun Kwak +4 more
wiley +1 more source