Results 181 to 190 of about 146,285 (261)

Inhibition of endocytosis by glycans arises from steric rather than electrostatic repulsion. [PDF]

Biophys J
Kamatar A, Villalobos JA, Hayden CC, Rodriguez Flores FG, Archer-Hartmann S, Azadi P, Belardi B, Parekh SH, Stachowiak JC.   +8 more
europepmc   +1 more source

Tailoring Amine Substitution in Fluorene and Dibenzothiophene: A Molecular Strategy for Ultralong Organic Phosphorescence

Advanced Optical Materials, EarlyView.
Tailored amine substitution in fluorene and dibenzothiophene derivatives enables systematic control of excited‐state properties and triplet population. Combined photophysical studies, TD‐DFT calculations and time‐resolved EPR reveal how charge‐transfer character, sulfur‐induced spin–orbit coupling and triplet manifold engineering cooperate to promote ...
Francesco Ruighi, Gianluca Accorsi, Eduardo Fabiano, Lorenzo Franco, Alessandro Agostini, Samuel Zatta, Leonard E. Cleve, Federica Angilè, Francesco Paolo Fanizzi, Gustavo Fernández, Agostina L. Capodilupo   +10 more
wiley   +1 more source

Design principles for enantiospecific <i>para</i>- and <i>ortho</i>-[3,3] rearrangements of chiral aryl-allyl ethers.

Org Chem Front
Breinsperger J, Kaiser M, Gärtner P.
europepmc   +1 more source

Molecular conformation engineering in central 8π-electron system toward unique aggregation-induced ultra-narrowband emission with a FWHM of 13 nm. [PDF]

Light Sci Appl
Liu L, Zhang H, Xiao C, Ma B, Li B, He X, Xiao G, Zou B, Tang B, Zhang H, Lam JWY, Tang BZ, Wang Z.   +12 more
europepmc   +1 more source

Regioselective π‐Extension of Helical PAHs: Tuning Energy Gaps and Excited‐State Dynamics Directed by Clar's Sextet Migration

Advanced Optical Materials, EarlyView.
Central and terminal ring fusions of per‐peri‐perbenzo[7]helicene (PB[7]H) yield novel helical polycyclic aromatic hydrocarbons (HPAHs). The migration of Clar's aromatic sextets governs the inner‐rim stiffness. This topology‐directed strategy bridges the discrete optical gaps of homologous series. Transition moment density (TMD) analysis visualizes the
Zhibo Liu, Zheng Zhang, Hikaru Sotome, Takashi Hirose   +3 more
wiley   +1 more source

A Machine Learning-Guided Study of Structure-Reactivity Relationships in Diels-Alder Cycloadditions. [PDF]

J Org Chem
Mahdian A, Farshadfar K, Laasonen K.
europepmc   +1 more source

Molecular Appendix Adjusted Architectural Propagations of Red‐Light Controlled Macroscopic Photoactuating Performances

Advanced Robotics Research, EarlyView.
Amphiphilic chloroazobenzenes, bearing different amino acids as end groups alanine, phenylalanine, and valine, exhibit excellent photoisomerizations. Varying structures of three amino acid groups participate in supramolecular formations and therefore photoinduced morphological transformations via adjusting intermolecular interactions. These interaction
Shuangshuang Meng, Ming‐Hin Chau, Takashi Kajitani, Franco King‐Chi Leung   +3 more
wiley   +1 more source

Expanding the toolbox: Emerging antisense oligonucleotide mechanisms for modulating gene expression. [PDF]

Mol Ther Nucleic Acids
Trew I, Wilton SD, Cale JM, Aung-Htut M.
europepmc   +1 more source

In Situ Photopolymerization of Smectic B Liquid‐Crystalline Electrolytes from Mesogenic Phosphate–Diacrylate/Ionic Liquid Complexes for High‐Performance Soft Ionic Actuators

Advanced Robotics Research, EarlyView.
A flexible liquid‐crystalline electrolyte membrane via in situ photopolymerization of a phosphate‐functionalized mesogen, ionic liquid, and diacrylate monomer is developed. The resulting smectic B (SmB)‐phase structure enables 2D ion transport with high conductivity (10−4 S cm−1).
Chengyang Liu, Masafumi Yoshio
wiley   +1 more source

Reaction of Hydrogermanes ArGeH₃ with Organolithium Reagents RLi: Unexpected Transfer of Organic Groups Instead of Lithiation. [PDF]

Inorg Chem
Schmid P, Leuprecht P, Schaffler-Glössl AM, Lee VY, Uhlig F.   +4 more
europepmc   +1 more source