Results 31 to 40 of about 9,420,423 (308)

Effect of polarity and steric on the rate addition of free radicals to Alkenes [PDF]

open access: yesKirkuk Journal of Science, 2009
In this investigation, the effective factors on the addition rate for hydroxy methyl and cynomethyl free radicals to some alkenes have been studied using quantum mechanics methods. Where in this study, physical properties like the electron density on the
Najla.J. Khalil, Mostafa.R. Aeyd
doaj   +1 more source

Steric charge

open access: yes, 2018
Steric charge is an informative descriptor providing novel insights to appreciate the steric effect and stereoselectivity for chemical processes and transformations.
Donghai Yu   +4 more
core   +1 more source

Exploring the sequence–structure relationship for amyloid peptides [PDF]

open access: yes, 2012
Amyloid fibril formation is associated with misfolding diseases, as well as fulfilling a functional role. The cross-β molecular architecture has been reported in increasing numbers of amyloid-like fibrillar systems. The Waltz algorithm is able to predict
Morris, Kyle L.   +14 more
core   +1 more source

Evaluation of an Appropriate Parameter for Steric Effect

open access: yes, 1980
Department of Chemistry, Sambalpur University, Buria-768 017 Manuscript received 8 January 1979, accepted 9 January 1980 The observed pKa values of eight sets of substituted organic acids have been fitted to the equation, pKa =\(P_i^o\) + α if j Fk ...
G. B. BEHERA, S. C. DASH
core   +1 more source

Salmonella lipopolysaccharide‐containing supported lipid bilayers as platforms to study bacteriophage interactions

open access: yesFEBS Letters, EarlyView.
We present robust protocols for the preparation of supported lipid bilayers (SLBs) incorporating either Salmonella smooth LPS or outer membrane vesicles (OMVs). We use a combination of quartz crystal microbalance with dissipation (QCM‐D) and fluorescence microscopy to both characterize the SLBs of various compositions and to probe their interactions ...
Hudson P. Pace   +6 more
wiley   +1 more source

Enhancing Structural Control in Covalent Organic Frameworks through Steric Interaction-Driven Linker Design [PDF]

open access: yes, 2023
Covalent Organic Frameworks (COFs) exhibiting kagome (kgm) structures are promising crystalline porous materials with two distinct pores. However, the challenge arises from the potential formation of the polymorphic square-lattice (sql) structure, which ...
Panagiotis, Kastritis   +5 more
core   +1 more source

Structure‐forward targeting of claudins with synthetic binders

open access: yesFEBS Letters, EarlyView.
Claudins form the paracellular barriers between epithelial and endothelial tissues at tight junctions and are targets for molecular binders with the goal of modulating barrier permeability. Claudin‐binding molecules are relevant in drug delivery or in altering claudin interactions with disease‐causing proteins.
Alex J. Vecchio
wiley   +1 more source

Electronic and Steric Effects on Oxygen Reactivities of NiFeSe Complexes Related to O2-Damaged [NiFeSe]-Hydrogenases’ Active Site

open access: yesInorganics
Hydrogen has the potential to serve as a new energy resource, reducing greenhouse gas emissions that contribute to climate change. Natural hydrogenases exhibit impressive catalytic abilities for hydrogen production, but they often lack oxygen tolerance ...
Yuchen Qiao   +4 more
doaj   +1 more source

Engineering peptides into antibodies—opportunities and strategies for therapeutic innovation

open access: yesFEBS Letters, EarlyView.
Peptides and antibodies occupy complementary therapeutic niches. Peptides recognize difficult targets in a compact format, while antibodies add specificity, long half‐life, and effector functions. This review examines strategies that merge both modalities—peptide grafting into loops, terminal and Fc fusions, and bioconjugation—highlighting how ...
Jinling Wang   +2 more
wiley   +1 more source

Influência de efeitos estéricos na hidrólise ácida de o-alquil acetais do benzaldeído [PDF]

open access: yes, 2003
Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas. Programa de Pós-Graduação em Química.Investigação de efeitos estéricos sobre o centro reacional na hidrólise ácida de O-alquil acetais do benzaldeído ...
Belarmino, Alexanders Tadeu das Neves
core  

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