Results 71 to 80 of about 9,420,423 (308)
Observation of 1,3-Diketones Formation in the Reaction of Bulky Acyl Chlorides with Methyllithium
The formation of 1,3-diketones was observed in the reactions of bulky acyl chlorides with methyllithium. The reaction products depend on the steric hindrance around the carbonyl group of the acyl chloride and the electronic effect of the group(s) linked ...
Liwen Yang, Nianfa Yang, Jian Zhang
doaj +1 more source
Biophysical characterisation shows that NanX, a membrane transport protein from the major facilitator superfamily (MFS), forms both monomers and dimers after purification. AlphaFold modelling and substrate docking provide information on residues likely involved in substrate recognition for NanX and another MFS member, NanT.
Michael C. Newton‐Vesty +13 more
wiley +1 more source
In silico and in vitro exploration of a tyrosinase for biocatalytic production of catechols
Tyrosinase from Ralstonia pseudosolanacearum is a promising biocatalyst for producing valuable catechols from monophenol substrates. This tyrosinase is uniquely suited to this due to its high monophenolase : diphenolase ratio. We combined in silico docking and in vivo kinetic characterisation of this tyrosinase with 11 industrially relevant monophenols,
James Britton +6 more
wiley +1 more source
A Dramatic Steric Effect on the Rate of Migratory CO Insertion on Rhodium
A Dramatic Steric Effect on the Rate of Migratory CO Insertion on ...
Luca Gonsalvi (1676023) +4 more
core +1 more source
In this study, a novel esterase from the thermoacidophilic archaeon Thermoplasma acidophilum was biochemically and structurally characterized. Our results demonstrate that Ta0887 is a highly thermostable esterase that preferentially hydrolyzes p‐nitrophenyl hexanoate and possesses an α‐helical cap domain that likely contributes to its substrate ...
Alejandro Delgado‐Rey +4 more
wiley +1 more source
Rejection characteristics of arsenic compounds such as arsenite, dimethyl arsinic acid, and arsenate were examined regarding the effect of pH change in nanofiltration.
H. Kitawaki +5 more
core +1 more source
How Might Exodus Effect Assist Users?
Exodus Effect approach is rather than something THC supply gave to people. CBD (in any structure) animates receptor webweb destinations withinside the endocannabinoids while consumed.
Exodus Effect
core +1 more source
Human ABCE1 cannot functionally replace its yeast ortholog. Yeast–human chimera analysis identified NBD1 as a major interspecies barrier. Genetic screening yielded hABCE1 revertants that rescue yeast viability but fail to suppress aberrant translation reinitiation in the 3′ UTR.
Eriko Nakata +3 more
wiley +1 more source
Very Strong Hydrogen Bond in Nitrophthalic Cocrystals
This work presents the studies of a very strong hydrogen bond (VSHB) in biologically active phthalic acids. Research on VSHB comes topical due to its participation in many biological processes.
Kinga Jóźwiak +5 more
doaj +1 more source
Steric shielding effects are seldom adopted in the stereocontrol with chiral primary amine catalysts. An unexpected steric shielding effect of protonated tertiary amine, a typical hydrogen-bonding moiety, was disclosed.
Yaning Wang (2997282) +5 more
core +1 more source

