Results 81 to 90 of about 146,285 (261)

Bridging Polymer Brushes and Coatings Through Ultra‐Thick Growth by Surface‐Initiated Photoiniferter Polymerization

open access: yesAdvanced Functional Materials, EarlyView.
Surface‐initiated photoiniferter‐mediated polymerization (SI‐PIMP) enables the controlled growth of UHMW polymer brushes with multi‐micrometer thicknesses, bridging conventional brushes and bulk‐like coatings. UHMW brushes are synthesized through a controlled/living process; they provide low friction and enhanced wear resistance under aqueous ...
Elena Avanzini   +8 more
wiley   +1 more source

Design and Construction of Novel Frustrated Lewis Pairs Based on Modified Lewis Acid B(C6F5)3

open access: yesCrystals
This study aims to systematically investigate the influence of substituent effects on the strength of Lewis acid–base interactions in frustrated Lewis pairs (FLPs). Specifically, -C6F5 groups of the classical Lewis acid B(C6F5)3 are sequentially replaced
Quanwei Wang   +5 more
doaj   +1 more source

Conformational Switching of Proteins on Material Surfaces Enabled by Peptide‐Oriented Adsorption

open access: yesAdvanced Functional Materials, EarlyView.
Responsive biointerfaces could be achieved using conformationally responsive proteins; however, their interconversion can be lost upon surface adsorption. Herein, we demonstrate that the incorporation a Au binding peptide into calmodulin allows for binding control on Au wherein the protein retains conformational switching. This capability was confirmed
Sakthirupini Ramamurthy   +7 more
wiley   +1 more source

Multifunctional Solid Polymer Electrolyte Films Integrating Intrinsic Self‐Healing and Dual Photo‐/pH‐Responsive Ionic Sensing for Intelligent Flexible Electronics

open access: yesAdvanced Functional Materials, EarlyView.
Multifunctional solid polymer electrolyte (SPE) films integrating intrinsic self‐healing, mechanical stretchability, and dual photo‐ and pH‐responsive ionic conductivity are developed. Constructed from thermoplastic polyurethane (TPU) and hydrogen‐bonded poly(thiourea triethylene glycol) (PTUEG3), these films form a dynamic supramolecular network ...
Mei‐Li Li   +12 more
wiley   +1 more source

Molecular Rotors: From Newtonian Fluids to Functional Materials as Viscosity and Temperature Sensing Tools

open access: yesAdvanced Functional Materials, EarlyView.
Molecular rotors are fluorescent molecules that are sensitive to viscosity and temperature variations in the environment. They exhibit a direct correlation between fluorescence and viscosity within Newtonian fluids. However, this correlation becomes less straightforward in complex systems.
Flavia Di Scala   +6 more
wiley   +1 more source

Electrostatic Superlattices Beyond 1:1 Stoichiometry

open access: yesAdvanced Functional Materials, EarlyView.
Polymer‐mediated charge regulation drives two hierarchical routes to higher‐stoichiometry nanoparticle superlattices. Tuning the polymer's molecular weight promotes progressive interstitial filling, transforming ZnS into the fully occupied CaF2${\rm CaF}_2$ lattice. Exchanging polymer assignment between large and small nanoparticles instead breaks CsCl
Binay P. Nayak   +7 more
wiley   +1 more source

Steric and Conformational Effects in Molecular Junctions

open access: yesChemistry – An Asian Journal
AbstractMolecular junctions, which comprise molecules bridging two electrodes, have emerged as valuable tools for investigating the conducting properties of molecules. Although electronic effects have been extensively investigated in molecular junctions, steric and conformational effects remain underexplored.
openaire   +2 more sources

Charge‐Tunable Coacervate Micelles for Separator Engineering in Lithium‐Sulfur Batteries

open access: yesAdvanced Functional Materials, EarlyView.
A separator engineering strategy based on charge‐tunable complex coacervate core micelles (C3Ms) is presented to form an ion‐selective layer regulating polysulfide transport in Li–S batteries. The micelles enable uniform adsorption onto commercial polypropylene separators and infiltration throughout the internal pore network, suppressing polysulfide ...
Yongsheng Zhang   +11 more
wiley   +1 more source

Balancing Hydrophobicity and Hydrophilicity: Dual Filler‐Engineered Proton Exchange Membranes for Durable, High‐Power Fuel Cells

open access: yesAdvanced Functional Materials, EarlyView.
Polarity‐matched Zr–MOFs program Nafion's nanoscale morphology during solution casting. Hydrophilic UiO‐66 preserves hydrated pathways, while hydrophobic UiO‐67 increases the proton hopping sites by densifying ionic clusters. Combining both fillers yields a membrane that delivers 176 mS cm−1 conductivity, reaches 1.46 W cm−2 under 200 kPa, and triples ...
Yonghwi Cho   +13 more
wiley   +1 more source

Bacterial Cellulose‐Based Bilayer Passive Cooler for High‐Performance Radiative/Evaporative Cooling

open access: yesAdvanced Functional Materials, EarlyView.
A sustainable bilayer passive cooler based on bacterial cellulose integrates radiative and evaporative cooling for efficient zero‐energy temperature reduction. The scalable, low‐carbon material shows strong potential for food preservation, low‐temperature storage, and cold‐chain logistics.
Yibing Zhang   +6 more
wiley   +1 more source

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